Near-infrared-absorbing B–N lewis pair-functionalized anthracenes: electronic structure tuning, conformational isomerism, and applications in photothermal cancer …

K Liu, Z Jiang, RA Lalancette, X Tang… - Journal of the American …, 2022 - ACS Publications
B–N-fused dianthracenylpyrazine derivatives are synthesized to generate new low gap
chromophores. Photophysical and electrochemical, crystal packing, and theoretical studies …

Catalytic enantioselective construction of chiroptical boron-stereogenic compounds

B Zu, Y Guo, C He - Journal of the American Chemical Society, 2021 - ACS Publications
The construction of main group heteroatom-stereogenic compounds is of great importance
due to their intriguing chemical, physical, biological, and stereoelectronic properties. Despite …

Linear Extension of Anthracene via B←N Lewis Pair Formation: Effects on Optoelectronic Properties and Singlet O2 Sensitization

M Vanga, A Sahoo, RA Lalancette… - Angewandte Chemie …, 2022 - Wiley Online Library
The functionalization of polycyclic aromatic hydrocarbons (PAHs) via B← N Lewis pair
formation offers an opportunity to judiciously fine‐tune the structural features and …

[HTML][HTML] Recent Advances in the Synthesis of Borinic Acid Derivatives

M Boyet, L Chabaud, M Pucheault - Molecules, 2023 - mdpi.com
Borinic acids [R2B (OH)] and their chelate derivatives are a subclass of organoborane
compounds used in cross-coupling reactions, catalysis, medicinal chemistry, polymer or …

Four-membered C^ N chelation in main-group organometallic chemistry

R Kannan, V Chandrasekhar - Dalton Transactions, 2023 - pubs.rsc.org
Main-group organometallic compounds containing four-membered C^ N chelating rings are
being studied because of the interest in harnessing the enhanced reactivity of such …

Weak Electron-Deficient Building Block Containing O–B← N Bonds for Polymer Donors

X Wang, X Tan, G Luo, J Huang, G Chen - Macromolecules, 2022 - ACS Publications
To date, almost all of the B← N embedded units are consciously designed to build polymer
acceptors due to their strong electron-deficient nature. In this work, we designed an O–B← N …

N–B← N Bridged bithiophene: A building block with reduced band gap to design n-type conjugated polymers

X Shao, J Wang, TB Marder, Z Xie, J Liu… - Macromolecules, 2021 - ACS Publications
The development of conjugated polymers with excellent performance of optoelectronic
device depends to a large extent on the molecular design of electron-accepting (A) building …

Pyrrolic type N directed borylation route to BN-PAHs: tuning the photophysical properties by varying the conjugation shape and size

Y Zhang, C Zhang, Y Guo, J Ye, B Zhen… - The Journal of …, 2021 - ACS Publications
Two series of BN-cyclopenta [a] phenalenes have been synthesized through an
indole/pyrrole oriented borylation reaction. A total of five compounds are obtained and fully …

Near‐Infrared Emissive B‐N Lewis Pair‐Functionalized Anthracenes via Selective LUMO Delocalization in Extended Conjugated Dimer and Polymer

J Zuo, K Liu, J Harrell, L Fang, P Piotrowiak… - Angewandte …, 2024 - Wiley Online Library
Acenes are attractive as building blocks for low gap organic materials with applications, for
example, in organic light emitting diodes, solar cells, bioimaging and diagnostics …

Manipulating MLCT transition character with ppy-type four-coordinate organoboron skeleton for highly efficient long-wavelength Ir-based phosphors in organic light …

Z Feng, Y Yu, X Yang, Y Sun, D Zhong… - Journal of Materials …, 2021 - pubs.rsc.org
Inspired by the intriguing optoelectronic characteristics of the 2-phenylpyridine-type (ppy-
type) four-coordinate organoboron skeleton, we envisage a molecular design strategy by …