Conjugated enynes are of great importance in organic synthesis, biochemistry and materials
sciences. The most commonly used synthetic methods include cross coupling reactions and …

Efficient iron‐catalyzed homocoupling of terminal alkynes and cross‐dimerization of aryl
acetylenes with trimethylsilylacetylene is reported. The complex [Fe (H)(BH4)(iPr‐PNP)](1) …

This review will outline the recent advances in chemo-, regio-, and stereoselective (cross-)
dimerization of terminal alkynes to generate 1, 3-enynes using different types of iron and …

A zirconium-catalyzed hydroaminoalkylation of alkynes to access α, β, γ-substituted allylic
amines in an atom-economic fashion is reported. The reaction is compatible with N …

1, 3-Enynes are core structures of various natural products or pharmaceuticals and are
broadly used synthons in organic synthesis. Metal-catalyzed alkyne dimerization is a …

We report a gem‐specific homo‐and cross‐dimerization of terminal alkynes catalyzed by a
well‐defined iron (II) complex containing Cp* and picolyl N‐heterocyclic carbene (NHC) …

We report the syntheses and catalytic activity of a series of piano-stool iron complexes with
the general formula [FeClCp*(NHC)](where NHC= N-heterocyclic carbene) toward the gem …

An air-stable rhodium (I)–oxygen adduct featuring a CNC-pincer ligand, based on 1, 2, 3-
triazol-5-ylidenes, catalyzes the homo-dimerization and hydrothiolation of alkynes, affording …

Atom‐economic and regioselective C− C bond formation has been achieved by rapid C− H
alkylation of unprotected secondary arylamines with unactivated alkenes. The combination …

Pd‐catalyzed hydroalkynylations were developed that involve ligand‐enabled
regiodivergent addition of an alkyne to an allenamide, giving branched and linear products …