Fundamentals and applications of polymer brushes in air

GC Ritsema van Eck, L Chiappisi… - ACS Applied Polymer …, 2022 - ACS Publications
For several decades, high-density, end-tethered polymers, forming so-called polymer
brushes, have inspired scientists to understand their properties and to translate them to …

Friends, foes, and favorites: relative interactions determine how polymer brushes absorb vapors of binary solvents

LA Smook, GC Ritsema van Eck, S de Beer - Macromolecules, 2020 - ACS Publications
Polymer brushes can absorb vapors from the surrounding atmosphere, which is relevant for
many applications such as in sensing and separation technologies. In this article, we report …

Beyond the Conventional Paradigm of Radial (Normal) Stretching of Tethered Chains. Do Theories of Micellization in Solutions of Block Copolymers Need to Be …

VS Kravchenko, IV Portnov, II Potemkin - Macromolecules, 2023 - ACS Publications
We have studied conformations of a single tethered chain, chains in a planar brush, and
corona-forming blocks in diblock copolymer micelles using dissipative particle dynamics …

Self-assembly of gradient copolymers in a selective solvent. New structures and comparison with diblock and statistical copolymers

VS Kravchenko, V Abetz, II Potemkin - Polymer, 2021 - Elsevier
We perform comparative studies of self-assembly of equivalent statistical, diblock and
gradient AB copolymers in a selective solvent using dissipative particle dynamics …

Electrostatic Fields Stimulate Absorption of Small Neutral Molecules in Gradient Polyelectrolyte Brushes

LA Smook, S de Beer - ChemPhysChem, 2023 - Wiley Online Library
Molecules can partition from a solution into a polymer coating, leading to a local enrichment.
If one can control this enrichment via external stimuli, one can implement such coatings in …

Free energies of polymer brushes with mobile anchors in a good solvent calculated with the expanded ensemble method

BF Faria, VV Palyulin, AM Vishnyakov - Colloids and Surfaces A …, 2022 - Elsevier
We explore the free energy of “mobile polymer brushes”: The polymer molecules are not
chemically bonded to the particle surface but are rather adsorbed by one end. They can …

[PDF][PDF] Untersuchung des adaptiven Benetzungsverhalten von quellbaren Poly-N-isopropylacrylamid Bürsten auf planaren Oberflächen

BA Fickel - tuprints.ulb.tu-darmstadt.de
Mit der Erforschung und Entwicklung von miniaturisierten Technologien wird die steuerbare
Benetzbarkeit von Oberflächen für mikrofluidische Module sowie in der medizinischen …