2, 2'-Bipyridyl Chelated Ru (II)-Annulated NHC Complex of 1-Methyl-2-Pyridin-2-Yl-2H-Imidazo [1, 5-a] Pyridin-4-Ylidene: Synthesis, Structure, Optical Properties, and …

BK Rana, J Dinda, PK Mahapatra, D Chopra… - Engineered …, 2022 - espublisher.com
This article depicts the synthesis of Ru (II)-NHC complex,[Ru (bpy)(NHC)(CH3CN) 2][PF6] 2
(2);[NHC= 1-methyl-2-(pyridyl) imidazo [1, 5-a] pyridine-2-yiledene] via Ag (I)-carbene trans …

Therapeutic potential of Ag (i)–, Au (i)–, and Au (iii)–NHC complexes of 3-pyridyl wingtip N-heterocyclic carbenes (NHCs) against lung cancer

PK Behera, L Maity, S Roy, A Das, P Sahu… - New Journal of …, 2023 - pubs.rsc.org
Herein, we report the easy synthetic approaches, structural features, theoretical studies, and
extensive bioactivity of [Ag (1) 2][PF6](2),[Au (1) 2][PF6](3), and [Au (1) Cl3](4) compounds …

[6,5] CNN Palladium(II) Pincer Complexes Containing N-Substituted Monoanionic and Dianionic Guanidinate Ligands: Syntheses, Structural Aspects, and Their Utility …

NK Sinha, N Thirupathi - Organometallics, 2021 - ACS Publications
The reactions of guanidines [(ArNH)(ArN═) CN (H)(C (O) Py-2)](Ar= 2-RC6H4; R= Me (1)
and CF3 (2)) with Pd (OC (O) R′) 2 (R′= Me, t Bu and CF3) were studied with a view …

Ru (II)‐based antineoplastic: A “wingtip” N‐heterocyclic carbene facilitates access to a new class of organometallics that are cytotoxic to common cancer cell lines

A Mondal, RK Tripathy, P Dutta… - Applied …, 2019 - Wiley Online Library
The syntheses, structures, and chemotherapeutic activities of Ag (I)‐, Au (I)‐, and Ru (II)‐
complexes ligated to a novel N‐heterocyclic carbene ligand, 2‐(4‐nitrophenyl) imidazo [1, 5 …

'Optimized route'to synthesize isoelectronic and isostructural Au (iii)-and Pt (ii)-NHC complexes: synthesis, structure, spectral properties, electrochemistry, and …

L Maity, S Barik, HK Kisan, A Jana, AA Isab… - New Journal of …, 2023 - pubs.rsc.org
We report the synthesis, structures, luminescent properties, and electrochemistry of gold (III)
and platinum (II)-N-heterocyclic carbene complexes. The proligand 1-methyl-2 …

Fine Tuning of Chiral Bis (N-heterocyclic carbene) Palladium Catalysts for Asymmetric Suzuki–Miyaura Cross-Coupling Reactions: Exploring the Ligand Modification

D Zhang, J Yu - Organometallics, 2020 - ACS Publications
Novel chiral N, N′-bisaryl bis (NHC) ligand precursors H2 [(S)-2] Cl2 on a spiro scaffold
and H2 [(S)-3b–g] Cl2 with a binaphthyl linkage were rationally designed and their …

From Pincer to Paddlewheel: C–H and C–S Bond Activation at Bis (2-pyridylthio) methane by Palladium (II)

P Halder, DJ SantaLucia, SV Park, JF Berry - Inorganic Chemistry, 2019 - ACS Publications
The bis (2-pyridylthio) methanidopalladium (II) pincer complex (1), containing a Pd–C bond,
was obtained from the reaction of bis (2-pyridylthio) methane (H2L) with palladium (II) …

Synthesis, crystal structure, spectral properties, molecular docking, and Hirshfeld surface analysis of [Ru (bpy) 2 (NHC)(AN)]+ 2

A Mondal, P Sahu, S Barik, HK Kisan, AA Isab… - Journal of Molecular …, 2024 - Elsevier
Here we present the synthesis, structures, and luminescent properties of Ru (II)-N-
heterocyclic carbene (NHC) complexes fastened with 2, 2/-bipyridine (bpy). Capitalizing …

Synthesis, structures, electrochemical characterizations, theoretical and anticancer studies of Pd (II)-, Pt (II)-NHC complexes

A Mondal, S Behera, HK Kisan, AA Isab… - Inorganica Chimica …, 2024 - Elsevier
We present the synthesis of two novel cationic Pd (II)-and Pt (II)-complexes ligated to a new
C∩ N donor N-heterocyclic carbene (NHC) ligand 3-methyl-1-(1-methyl-2-methylbenzoyl) …

Bipyridyl/carbazolate silver (I) and gold (I) N‐heterocyclic carbene complexes: A systematic study of geometric constraints and electronic properties

S Das Adhikary, A Mondal, HK Kisan… - Applied …, 2020 - Wiley Online Library
A series of silver (I) and gold (I) carbene complexes of the type [M (L)(2, 2′‐
bipyridine)][PF6](L= 1‐benzyl‐3‐(2‐pyridylmethyl) benzimidazolylidene; M= Ag (1); M= Au …