Research progress on NH3-SCR mechanism of metal-supported zeolite catalysts

W ZHANG, J CHEN, GUO Li, W ZHENG… - Journal of Fuel …, 2021 - Elsevier
Metal-supported zeolite catalysts have been widely used in the NH 3 selective catalytic
reduction (NH 3-SCR) reactions due to their wide temperature window and good …

Lessons from nature: a bio-inspired approach to molecular design

SA Cook, EA Hill, AS Borovik - Biochemistry, 2015 - ACS Publications
Metalloproteins contain actives sites with intricate structures that perform specific functions
with high selectivity and efficiency. The complexity of these systems complicates the study of …

Dramatically accelerated selective oxygen-atom transfer by a nonheme iron (IV)-oxo complex: tuning of the first and second coordination spheres

LR Widger, CG Davies, T Yang… - Journal of the …, 2014 - ACS Publications
The new ligand N3PyamideSR and its FeII complex [FeII (N3PyamideSR)](BF4) 2 (1) are
described. Reaction of 1 with PhIO at− 40° C gives metastable [FeIV (O)(N3PyamideSR)] …

Redox activity and π bonding in a tripodal seven-coordinate molybdenum (VI) tris (amidophenolate)

T Marshall-Roth, SN Brown - Dalton Transactions, 2015 - pubs.rsc.org
A tris (aminophenol), tris (2-(3′, 5′-di-tert-butyl-2′-hydroxyphenyl) amino-4-
methylphenyl) amine, MeClampH6, is prepared in three steps from tri-p-tolylamine. The …

Thermodynamics of Proton and Electron Transfer in Tetranuclear Clusters with Mn–OH2/OH Motifs Relevant to H2O Activation by the Oxygen Evolving Complex in …

CJ Reed, T Agapie - Journal of the American Chemical Society, 2018 - ACS Publications
We report the synthesis of site-differentiated heterometallic clusters with three Fe centers
and a single Mn site that binds water and hydroxide in multiple cluster oxidation states …

Thioether-ligated iron (II) and iron (III)-hydroperoxo/alkylperoxo complexes with an H-bond donor in the second coordination sphere

LR Widger, Y Jiang, AC McQuilken, T Yang… - Dalton …, 2014 - pubs.rsc.org
The non-heme iron complexes,[FeII (N3PySR)(CH3CN)](BF4) 2 (1) and [FeII
(N3PyamideSR)](BF4) 2 (2), afford rare examples of metastable Fe (III)-OOH and Fe (III) …

金属负载型分子筛催化剂的NH3-SCR机理研究进展

张文博, 陈佳玲, 郭立, 郑伟, 王光华, 郑申棵… - 燃料化学学报(中 …, 2021 - rlhxxb.sxicc.ac.cn
在NH 3 选择性催化还原(NH 3-SCR) 反应中, 由于具有宽温度窗口和良好的水热稳定性,
金属负载型分子筛是具有广泛应用潜力的脱硝催化剂. 本文综述了Cu 基和Fe …

Theoretical studies on concerted versus two steps hydrogen atom transfer reaction by non-heme Mn IV/III [double bond, length as m-dash] O complexes: how …

M Jaccob, A Ansari, B Pandey, G Rajaraman - Dalton Transactions, 2013 - pubs.rsc.org
High-valent metal–oxo complexes have been extensively studied over the years due to their
intriguing properties and their abundant catalytic potential. The majority of the catalytic …

Manganese–Hydroxido Complexes Supported by a Urea/Phosphinic Amide Tripodal Ligand

VF Oswald, AC Weitz, S Biswas, JW Ziller… - Inorganic …, 2018 - ACS Publications
Hydrogen bonds (H-bonds) within the secondary coordination sphere are often invoked as
essential noncovalent interactions that lead to productive chemistry in metalloproteins …

Synthesis and Characterization of a Masked Terminal Nickel‐Oxide Complex

P Heim, G Spedalotto, M Lovisari… - … A European Journal, 2023 - Wiley Online Library
In exploring terminal nickel‐oxo complexes, postulated to be the active oxidant in natural
and non‐natural oxidation reactions, we report the synthesis of the pseudo‐trigonal …