Confinement of luminescent guests in metal–organic frameworks: understanding pathways from synthesis and multimodal characterization to potential applications of …

M Gutiérrez, Y Zhang, JC Tan - Chemical Reviews, 2022 - ACS Publications
This review gives an authoritative, critical, and accessible overview of an emergent class of
fluorescent materials termed “LG@ MOF”, engineered from the nanoscale confinement of …

Power of infrared and raman spectroscopies to characterize metal-organic frameworks and investigate their interaction with guest molecules

KI Hadjiivanov, DA Panayotov, MY Mihaylov… - Chemical …, 2020 - ACS Publications
The variety of functionalities and porous structures inherent to metal-organic frameworks
(MOFs) together with the facile tunability of their properties makes these materials suitable …

A sol–gel monolithic metal–organic framework with enhanced methane uptake

T Tian, Z Zeng, D Vulpe, ME Casco, G Divitini… - Nature materials, 2018 - nature.com
A critical bottleneck for the use of natural gas as a transportation fuel has been the
development of materials capable of storing it in a sufficiently compact form at ambient …

Defibrillation of soft porous metal-organic frameworks with electric fields

A Knebel, B Geppert, K Volgmann, DI Kolokolov… - Science, 2017 - science.org
Gas transport through metal-organic framework membranes (MOFs) was switched in situ by
applying an external electric field (E-field). The switching of gas permeation upon E-field …

Elucidation of flexible metal-organic frameworks: Research progresses and recent developments

JH Lee, S Jeoung, YG Chung, HR Moon - Coordination Chemistry Reviews, 2019 - Elsevier
Flexibility is a unique property of metal-organic frameworks (MOFs) that differentiates them
from other rigid inorganic porous materials such as zeolites and porous silica. Flexible …

Exploring the Structural, Dynamic, and Functional Properties of Metal‐Organic Frameworks through Molecular Modeling

F Formalik, K Shi, F Joodaki, X Wang… - Advanced Functional …, 2023 - Wiley Online Library
This review spotlights the role of atomic‐level modeling in research on metal‐organic
frameworks (MOFs), especially the key methodologies of density functional theory (DFT) …

[HTML][HTML] Strong coupling of collective intermolecular vibrations in organic materials at terahertz frequencies

R Damari, O Weinberg, D Krotkov, N Demina… - Nature …, 2019 - nature.com
Several years ago, strong coupling between electronic molecular transitions and photonic
structures was shown to modify the electronic landscape of the molecules and affect their …

MOFs in the time domain

DJ Cerasale, DC Ward, TL Easun - Nature Reviews Chemistry, 2022 - nature.com
Many of the proposed applications of metal–organic framework (MOF) materials may fail to
materialize if the community does not fully address the difficult fundamental work needed to …

Investigating the function and design of molecular materials through terahertz vibrational spectroscopy

PA Banks, EM Kleist, MT Ruggiero - Nature Reviews Chemistry, 2023 - nature.com
Terahertz spectroscopy has proved to be an essential tool for the study of condensed phase
materials. Terahertz spectroscopy probes the low-frequency vibrational dynamics of atoms …

Metal–organic frameworks in modern physics: Highlights and perspectives

YA Mezenov, AA Krasilin, VP Dzyuba… - Advanced …, 2019 - Wiley Online Library
Owing to the synergistic combination of a hybrid organic–inorganic nature and a chemically
active porous structure, metal–organic frameworks have emerged as a new class of …