Decoupling ion transport and matrix dynamics to make high performance solid polymer electrolytes
Transport of ions through solid polymeric electrolytes (SPEs) involves a complicated
interplay of ion solvation, ion–ion interactions, ion-polymer interactions, and free volume …
interplay of ion solvation, ion–ion interactions, ion-polymer interactions, and free volume …
Visualizing slow internal relaxations in a two-dimensional glassy system
Unlike a crystal, a glassy solid state displays slow internal relaxation processes besides
vibrational modes even when structural (α) relaxation is frozen. The precise nature of such …
vibrational modes even when structural (α) relaxation is frozen. The precise nature of such …
Can the microscopic and macroscopic transport phenomena in deep eutectic solvents be reconciled?
Deep eutectic solvents (DESs) have become ubiquitous in a variety of industrial and
pharmaceutical applications since their discovery. However, the fundamental understanding …
pharmaceutical applications since their discovery. However, the fundamental understanding …
Competing effects of cohesive energy and cross-link density on the segmental dynamics and mechanical properties of cross-linked polymers
X Zheng, Y Guo, JF Douglas, W Xia - Macromolecules, 2022 - ACS Publications
To develop structure–property relationships for cross-linked thermosetting polymers, it is
crucial to better understand key factors that control their segmental dynamics and …
crucial to better understand key factors that control their segmental dynamics and …
Fast dynamics in a model metallic glass-forming material
We investigate the fast β-and Johari–Goldstein (JG) β-relaxation processes, along with the
elastic scattering response of glass-forming (GF) liquids and the boson peak, in a simulated …
elastic scattering response of glass-forming (GF) liquids and the boson peak, in a simulated …
Point-defect avalanches mediate grain boundary diffusion
Grain boundary diffusion in polycrystalline materials is a physical phenomenon of great
fundamental interest and practical significance. Although accelerated atomic transport along …
fundamental interest and practical significance. Although accelerated atomic transport along …
[HTML][HTML] Understanding the role of cross-link density in the segmental dynamics and elastic properties of cross-linked thermosets
X Zheng, Y Guo, JF Douglas, W Xia - The Journal of Chemical Physics, 2022 - pubs.aip.org
Cross-linking is known to play a pivotal role in the relaxation dynamics and mechanical
properties of thermoset polymers, which are commonly used in structural applications …
properties of thermoset polymers, which are commonly used in structural applications …
Influence of chain stiffness on the segmental dynamics and mechanical properties of cross-linked polymers
X Zheng, W Nie, Y Guo, JF Douglas, W Xia - Macromolecules, 2023 - ACS Publications
We extend previous systematic investigations of a family of model coarse-grained polymer
network-forming materials by focusing on the influence of varying molecular rigidity on basic …
network-forming materials by focusing on the influence of varying molecular rigidity on basic …
Parallel emergence of rigidity and collective motion in a family of simulated glass-forming polymer fluids
X Xu, JF Douglas, WS Xu - Macromolecules, 2023 - ACS Publications
The emergence of the solid state in glass-forming materials upon cooling is accompanied by
changes in both thermodynamic and viscoelastic properties and by a precipitous drop in …
changes in both thermodynamic and viscoelastic properties and by a precipitous drop in …
[HTML][HTML] Crossover in dynamics in the Kob-Andersen binary mixture glass-forming liquid
Glass-forming liquids are broadly classified as being fragile or strong, depending on the
deviation from Arrhenius behavior of their relaxation times. A fragile to strong crossover is …
deviation from Arrhenius behavior of their relaxation times. A fragile to strong crossover is …