Decoupling ion transport and matrix dynamics to make high performance solid polymer electrolytes

SD Jones, J Bamford, GH Fredrickson… - ACS polymers …, 2022 - ACS Publications
Transport of ions through solid polymeric electrolytes (SPEs) involves a complicated
interplay of ion solvation, ion–ion interactions, ion-polymer interactions, and free volume …

Visualizing slow internal relaxations in a two-dimensional glassy system

Y Chen, Z Ye, K Wang, J Huang, H Tong, Y Jin… - Nature Physics, 2023 - nature.com
Unlike a crystal, a glassy solid state displays slow internal relaxation processes besides
vibrational modes even when structural (α) relaxation is frozen. The precise nature of such …

Can the microscopic and macroscopic transport phenomena in deep eutectic solvents be reconciled?

H Srinivasan, VK Sharma, S Mitra - Physical Chemistry Chemical …, 2021 - pubs.rsc.org
Deep eutectic solvents (DESs) have become ubiquitous in a variety of industrial and
pharmaceutical applications since their discovery. However, the fundamental understanding …

Competing effects of cohesive energy and cross-link density on the segmental dynamics and mechanical properties of cross-linked polymers

X Zheng, Y Guo, JF Douglas, W Xia - Macromolecules, 2022 - ACS Publications
To develop structure–property relationships for cross-linked thermosetting polymers, it is
crucial to better understand key factors that control their segmental dynamics and …

Fast dynamics in a model metallic glass-forming material

H Zhang, X Wang, HB Yu, JF Douglas - The Journal of Chemical …, 2021 - pubs.aip.org
We investigate the fast β-and Johari–Goldstein (JG) β-relaxation processes, along with the
elastic scattering response of glass-forming (GF) liquids and the boson peak, in a simulated …

Point-defect avalanches mediate grain boundary diffusion

I Chesser, Y Mishin - Communications Materials, 2022 - nature.com
Grain boundary diffusion in polycrystalline materials is a physical phenomenon of great
fundamental interest and practical significance. Although accelerated atomic transport along …

[HTML][HTML] Understanding the role of cross-link density in the segmental dynamics and elastic properties of cross-linked thermosets

X Zheng, Y Guo, JF Douglas, W Xia - The Journal of Chemical Physics, 2022 - pubs.aip.org
Cross-linking is known to play a pivotal role in the relaxation dynamics and mechanical
properties of thermoset polymers, which are commonly used in structural applications …

Influence of chain stiffness on the segmental dynamics and mechanical properties of cross-linked polymers

X Zheng, W Nie, Y Guo, JF Douglas, W Xia - Macromolecules, 2023 - ACS Publications
We extend previous systematic investigations of a family of model coarse-grained polymer
network-forming materials by focusing on the influence of varying molecular rigidity on basic …

Parallel emergence of rigidity and collective motion in a family of simulated glass-forming polymer fluids

X Xu, JF Douglas, WS Xu - Macromolecules, 2023 - ACS Publications
The emergence of the solid state in glass-forming materials upon cooling is accompanied by
changes in both thermodynamic and viscoelastic properties and by a precipitous drop in …

[HTML][HTML] Crossover in dynamics in the Kob-Andersen binary mixture glass-forming liquid

P Das, S Sastry - Journal of Non-Crystalline Solids: X, 2022 - Elsevier
Glass-forming liquids are broadly classified as being fragile or strong, depending on the
deviation from Arrhenius behavior of their relaxation times. A fragile to strong crossover is …