Recent advances in the functionalization of formyl and acroleyl appended corroles

I Yadav, D Dhiman, M Sankar - Chemical Communications, 2024 - pubs.rsc.org
The field of corrole systems particularly those with functional groups at their peripheral
positions has experienced a surge of interest in recent years, driven by their exceptional …

Panchromatic and Perturbed Absorption Spectral Features and Multiredox Properties of Dicyanovinyl-and Dicyanobutadienyl-Appended Cobalt Corroles

I Yadav, M Sankar - Inorganic Chemistry, 2023 - ACS Publications
Four new β-functionalized π-extended cobalt corroles with one and two dicyanovinyl (DCV)
or dicyanobutadienyl (DCBD) moieties at the 3-and 3, 17-positions have been synthesized …

Magnetic Circular Dichroism of Porphyrinoid Silver Complexes: Evidence of the Electronic Structure Inversion upon Protonation of the N-Confused Core

DE Nevonen, JC Wagner, C Brückner… - The Journal of …, 2023 - ACS Publications
We report a systematic investigation of a series of Ag (II) and Ag (III) complexes of porphyrins
and their analogues using UV–vis magnetic circular dichroism (MCD) spectroscopies and …

Highly Efficient β‐Functionalized Oxidomolybdenum (V) Corroles for Catalytic Oxidative Bromination of Phenols at Room Temperature

I Yadav, V Prakash, RR Kaswan… - European Journal of …, 2023 - Wiley Online Library
Two new β‐functionalized oxidomolybdenum (V) corroles, oxido [3‐formyl‐5, 10, 15‐
triphenylcorrolato] molybdenum (V)(Mo‐1) and oxido [3‐dicyanovinyl‐5, 10, 15 …

Enhanced Catalytic Activity of Binuclear Oxidovanadium (IV) Bisbenzimidazole Linked Porphyrin Dimer for the Generation of Biologically Active 3, 4 …

SK Yadav, A Patter, M Sankar - Inorganic Chemistry, 2024 - ACS Publications
Binuclear vanadyl (IV) porphyrin (V 2 BP), where two vanadium (IV) porphyrin macrocycles
are linked through benzimidazole units at the β-positions, has been prepared and …

Synthesis and Understanding of the Role of Donor-Tetracyanobutadiene in Porphyrin β-Periphery toward Ultrafast Charge Transfer Dynamics

AW Dawson, B Sekaran, S Das, R Misra… - The Journal of …, 2024 - ACS Publications
The porphyrins, structurally analogous to chlorophyll pigment, have drawn significant
interest in mimicking natural photosynthetic processes in energy conversion applications. In …

Inverse Hypercorroles

WR Osterloh, N Desbois, J Conradie, CP Gros… - Inorganic …, 2024 - ACS Publications
Ground-state and time-dependent density functional theory (TDDFT) calculations with the
long-range-corrected, Coulomb-attenuating CAMY-B3LYP exchange-correlation functional …

ICT-based fluorescent nanoparticles for selective cyanide ion detection and quantification in apple seeds

UR Gandra, R Lo, PB Managutti, AM Butt, PS Reddy… - Analyst, 2025 - pubs.rsc.org
In this report, we successfully engineered a novel probe based on an acceptor–donor–
acceptor (A–D–A) architecture featuring dicyanovinyl-substituted thieno [3, 2-b] thiophene …

Structurally influenced optical nonlinearities and ultrafast dynamics in β-acroleyl-and β-dicyanobutadienyl-appended cobalt corroles

I Yadav, JN Acharyya, GV Prakash… - Physical Chemistry …, 2024 - pubs.rsc.org
Structurally influenced optical nonlinearities and ultrafast dynamics in β-acroleyl- and β-dicyanobutadienyl-appended
cobalt corroles - Physical Chemistry Chemical Physics (RSC Publishing) DOI:10.1039/D4CP00090K …

[引用][C] Structural, photophysical, and electrochemical redox properties of meso-tetrakis(pentafluorophenyl)porphyrins

AK Deval, M Sankar - Journal of Porphyrins and Phthalocyanines, 2024 - World Scientific
This study delineates the synthesis and comprehensive characterization of metal complexes
of meso-tetrakis (pentafluorophenyl) porphyrin (H2TPF 2 0 P, 1) with first-row transition …