Visible light-induced transition metal catalysis

KPS Cheung, S Sarkar, V Gevorgyan - Chemical reviews, 2021 - ACS Publications
In recent years, visible light-induced transition metal catalysis has emerged as a new
paradigm in organic photocatalysis, which has led to the discovery of unprecedented …

Enantioselective radical reactions using chiral catalysts

S Mondal, F Dumur, D Gigmes, MP Sibi… - Chemical …, 2022 - ACS Publications
Benefiting from the impressive increase in fundamental knowledge, the last 20 years have
shown a continuous burst of new ideas and consequently a plethora of new catalytic …

Chiral photocatalyst structures in asymmetric photochemical synthesis

MJ Genzink, JB Kidd, WB Swords, TP Yoon - Chemical reviews, 2021 - ACS Publications
Asymmetric catalysis is a major theme of research in contemporary synthetic organic
chemistry. The discovery of general strategies for highly enantioselective photochemical …

Enantioselective photochemical reactions enabled by triplet energy transfer

J Großkopf, T Kratz, T Rigotti, T Bach - Chemical Reviews, 2021 - ACS Publications
For molecules with a singlet ground state, the population of triplet states is mainly possible
(a) by direct excitation and subsequent intersystem crossing or (b) by energy transfer from …

Enantioselective [2+ 2]-cycloadditions with triplet photoenzymes

N Sun, J Huang, J Qian, TP Zhou, J Guo, L Tang… - Nature, 2022 - nature.com
Naturally evolved enzymes, despite their astonishingly large variety and functional diversity,
operate predominantly through thermochemical activation. Integrating prominent …

Transition metal catalysis controlled by hydrogen bonding in the second coordination sphere

JNH Reek, B de Bruin, S Pullen, TJ Mooibroek… - Chemical …, 2022 - ACS Publications
Transition metal catalysis is of utmost importance for the development of sustainable
processes in academia and industry. The activity and selectivity of metal complexes are …

[HTML][HTML] Triplet energy transfer photocatalysis: unlocking the next level

F Strieth-Kalthoff, F Glorius - Chem, 2020 - cell.com
Energy transfer can leverage the enormous potential of excited-state reactivity. Through"
indirect excitation" of substrates, otherwise elusive reactivity modes can be switched on …

Synthesis of polysubstituted 2-oxabicyclo [2.1. 1] hexanes via visible-light-induced energy transfer

Y Liang, R Kleinmans, CG Daniliuc… - Journal of the American …, 2022 - ACS Publications
Synthesis of bicyclic scaffolds has attracted growing interest because they are of high
importance in modern pharmaceutical development. Here we report a strategy to access …

Energy transfer catalysis mediated by visible light: principles, applications, directions

F Strieth-Kalthoff, MJ James, M Teders… - Chemical Society …, 2018 - pubs.rsc.org
Harnessing visible light to access excited (triplet) states of organic compounds can enable
impressive reactivity modes. This tutorial review covers the photophysical fundamentals and …

Visible‐light‐induced organic photochemical reactions through energy‐transfer pathways

QQ Zhou, YQ Zou, LQ Lu… - Angewandte Chemie …, 2019 - Wiley Online Library
Visible‐light photocatalysis is a rapidly developing and powerful strategy to initiate organic
transformations, as it closely adheres to the tenants of green and sustainable chemistry …