Visible light-induced transition metal catalysis
In recent years, visible light-induced transition metal catalysis has emerged as a new
paradigm in organic photocatalysis, which has led to the discovery of unprecedented …
paradigm in organic photocatalysis, which has led to the discovery of unprecedented …
Enantioselective radical reactions using chiral catalysts
Benefiting from the impressive increase in fundamental knowledge, the last 20 years have
shown a continuous burst of new ideas and consequently a plethora of new catalytic …
shown a continuous burst of new ideas and consequently a plethora of new catalytic …
Chiral photocatalyst structures in asymmetric photochemical synthesis
Asymmetric catalysis is a major theme of research in contemporary synthetic organic
chemistry. The discovery of general strategies for highly enantioselective photochemical …
chemistry. The discovery of general strategies for highly enantioselective photochemical …
Enantioselective photochemical reactions enabled by triplet energy transfer
J Großkopf, T Kratz, T Rigotti, T Bach - Chemical Reviews, 2021 - ACS Publications
For molecules with a singlet ground state, the population of triplet states is mainly possible
(a) by direct excitation and subsequent intersystem crossing or (b) by energy transfer from …
(a) by direct excitation and subsequent intersystem crossing or (b) by energy transfer from …
Enantioselective [2+ 2]-cycloadditions with triplet photoenzymes
N Sun, J Huang, J Qian, TP Zhou, J Guo, L Tang… - Nature, 2022 - nature.com
Naturally evolved enzymes, despite their astonishingly large variety and functional diversity,
operate predominantly through thermochemical activation. Integrating prominent …
operate predominantly through thermochemical activation. Integrating prominent …
Transition metal catalysis controlled by hydrogen bonding in the second coordination sphere
Transition metal catalysis is of utmost importance for the development of sustainable
processes in academia and industry. The activity and selectivity of metal complexes are …
processes in academia and industry. The activity and selectivity of metal complexes are …
[HTML][HTML] Triplet energy transfer photocatalysis: unlocking the next level
F Strieth-Kalthoff, F Glorius - Chem, 2020 - cell.com
Energy transfer can leverage the enormous potential of excited-state reactivity. Through"
indirect excitation" of substrates, otherwise elusive reactivity modes can be switched on …
indirect excitation" of substrates, otherwise elusive reactivity modes can be switched on …
Synthesis of polysubstituted 2-oxabicyclo [2.1. 1] hexanes via visible-light-induced energy transfer
Y Liang, R Kleinmans, CG Daniliuc… - Journal of the American …, 2022 - ACS Publications
Synthesis of bicyclic scaffolds has attracted growing interest because they are of high
importance in modern pharmaceutical development. Here we report a strategy to access …
importance in modern pharmaceutical development. Here we report a strategy to access …
Energy transfer catalysis mediated by visible light: principles, applications, directions
F Strieth-Kalthoff, MJ James, M Teders… - Chemical Society …, 2018 - pubs.rsc.org
Harnessing visible light to access excited (triplet) states of organic compounds can enable
impressive reactivity modes. This tutorial review covers the photophysical fundamentals and …
impressive reactivity modes. This tutorial review covers the photophysical fundamentals and …
Visible‐light‐induced organic photochemical reactions through energy‐transfer pathways
QQ Zhou, YQ Zou, LQ Lu… - Angewandte Chemie …, 2019 - Wiley Online Library
Visible‐light photocatalysis is a rapidly developing and powerful strategy to initiate organic
transformations, as it closely adheres to the tenants of green and sustainable chemistry …
transformations, as it closely adheres to the tenants of green and sustainable chemistry …