The synthesis of diastereo-and enantiopure heterocyclic molecules via catalytic asymmetric
1, 3-dipolar cycloaddition reaction between azomethine ylides, generated in situ from α …

Direct C (sp2)–H functionalization of the endocyclic azomethine and aldonitrone moieties in
non-aromatic azaheterocycles has established itself as a promising methodology over the …

Biocatalytic approaches to the synthesis of optically pure chiral amines, starting from simple
achiral building blocks, are highly desirable because such motifs are present in a wide …

Triple for all: Various optically active anti‐β‐nitro propargylic alcohols are synthesized by the
catalytic stereoselective addition of nitroalkanes to ynals (the direct Henry reaction of ynals) …

A practical method for the synthesis of five-membered iminocyclitols, pyrrolidine alkaloids
bearing multiple hydroxyl substituents, has been developed. All of the eight key …

Pyrrolidine derivatives are a significant group of heterocycles which are present in an array
of natural and synthetic biologically active products.[1] Furthermore, proline analogues have …

We report herein a silver (I)-catalyzed exo-selective synthesis of highly substituted Δ1-
pyrroline scaffolds from amino acid-derived münchnones. Silver acetate successfully …

Hypervalent iodine compounds are viable reagents for the oxidation of N, N-disubstituted
hydroxylamines to the corresponding nitrones, with IBX performing best. The procedure is …

This review covers practical aspects of the preparation, handling and use of all types of
amine N-oxides. It aims to provide both an encyclopedic overview of the general chemistry …

The synthesis of enantiopure cyclic nitrones has become a frequently addressed topic in
discussions of their usefulness in the production of natural products and biologically active …