Nitric oxide (NO) is an important signaling molecule that is involved in a wide range of
physiological and pathological events in biology. Metal coordination chemistry, especially …

The metallobiochemistry underlying the formation of the inorganic N–N-bond-containing
molecules nitrous oxide (N2O), dinitrogen (N2), and hydrazine (N2H4) is essential to the …

The electroreduction of nitrogen to ammonia offers a promising alternative to the energy-
intensive Haber–Bosch process. Unfortunately, the reaction suffers from low activity and …

Aluminium oxides constitute an important class of inorganic compound that are widely
exploited in the chemical industry as catalysts and catalyst supports. Due to the tendency for …

The deoxygenative conversion of carbon dioxide to carbon monoxide is promoted by the
aluminyl anion [Al (NONAr)]−(NONAr=[O (SiMe2NAr) 2] 2−, Ar= 2, 6‐iPr2C6H3). The …

The oxides of nitrogen (chiefly NO, NO3−, NO2− and N2O) are key components of the
natural nitrogen cycle and are intermediates in a range of processes of enormous biological …

The weak-field ligand environments at the metal nodes of metal–organic frameworks (MOFs)
mimic the electronic environment of metalloenzyme active sites, but little is known about the …

Nitric oxide (NO) has a number of important biological functions, including nerve signaling
transduction, blood pressure control, and, at higher concentrations, immune defense. A …

Reduction of nitric oxide (NO) to nitrous oxide (N2O) is associated with immense biological
and health implications. Flavodiiron nitric oxide reductases (FNORs) are diiron containing …

Herein, we review the preparation and coordination chemistry of cis and trans isomers of
hyponitrite,[N2O2] 2–. Hyponitrite is known to bind to metals via a variety of bonding modes …