Controlled/living radical polymerization in dispersed systems: an update

PB Zetterlund, SC Thickett, S Perrier… - Chemical …, 2015 - ACS Publications
This review is an extensive update to the comprehensive review on controlled/living radical
polymerization (CLRP) in dispersed systems published in 2008. 1 A note on nomenclature …

Living radical polymerization by the RAFT process

G Moad, E Rizzardo, SH Thang - Australian journal of chemistry, 2005 - CSIRO Publishing
This paper presents a review of living radical polymerization achieved with thiocarbonylthio
compounds [ZC (= S) SR] by a mechanism of reversible addition–fragmentation chain …

Expanding the scope of RAFT polymerization: recent advances and new horizons

MR Hill, RN Carmean, BS Sumerlin - Macromolecules, 2015 - ACS Publications
Reversible deactivation radical polymerization (RDRP) has revolutionized modern polymer
chemistry over the past two decades, thus laying the groundwork for the synthesis of …

RAFT agent design and synthesis

DJ Keddie, G Moad, E Rizzardo, SH Thang - Macromolecules, 2012 - ACS Publications
This Perspective reviews the design and synthesis of RAFT agents. First, we briefly detail the
basic design features that should be considered when selecting a RAFT agent or macro …

[HTML][HTML] Radical addition–fragmentation chemistry in polymer synthesis

G Moad, E Rizzardo, SH Thang - Polymer, 2008 - Elsevier
This review traces the development of addition–fragmentation chain transfer agents and
related ring-opening monomers highlighting recent innovation in these areas. The major …

Investigating the effect of end-group, molecular weight, and solvents on the catalyst-free depolymerization of RAFT polymers: possibility to reverse the polymerization …

HS Wang, NP Truong, GR Jones… - ACS Macro …, 2022 - ACS Publications
Reversing reversible deactivation radical polymerization (RDRP) to regenerate the original
monomer is an attractive prospect for both fundamental research and industry. However …

Advances in RAFT polymerization: the synthesis of polymers with defined end-groups

G Moad, YK Chong, A Postma, E Rizzardo, SH Thang - Polymer, 2005 - Elsevier
This paper provides an overview and discusses some recent developments in radical
polymerization with reversible addition–fragmentation chain transfer (RAFT polymerization) …

Macromolecular design via reversible addition–fragmentation chain transfer (RAFT)/xanthates (MADIX) polymerization

S Perrier, P Takolpuckdee - Journal of Polymer Science Part A …, 2005 - Wiley Online Library
Among the living radical polymerization techniques, reversible addition–fragmentation chain
transfer (RAFT) and macromolecular design via the interchange of xanthates (MADIX) …

Controlled/living radical polymerization in dispersed systems

PB Zetterlund, Y Kagawa, M Okubo - Chemical reviews, 2008 - ACS Publications
1.2 Background Radical polymerization is of enormous industrial importance; approximately
50% of all commercial polymers are produced by radical polymerization.(23) The process is …

Ab initio emulsion polymerization by RAFT-controlled self-assembly

CJ Ferguson, RJ Hughes, D Nguyen, BTT Pham… - …, 2005 - ACS Publications
A method is developed to enable emulsion polymerization to be performed under RAFT
control to give living character without the problems that often affect such systems: formation …