Human milk oligosaccharides as bioactive compounds in infant formula: recent advances and trends in synthetic methods

E Pérez-Escalante, S Alatorre-Santamaría… - Critical Reviews in …, 2022 - Taylor & Francis
Human milk oligosaccharides (HMO) have attracted great interest in recent years due to
their role in boosting infants and adults health. According to several in vitro, in vivo and …

Synthesis of glycoconjugate benzothiazoles via cleavage of benzotriazole ring

D Kumar, A Mishra, BB Mishra… - The Journal of …, 2013 - ACS Publications
A concise and efficacious benzotriazole-mediated novel two-step protocol has been
developed for easy access to glycoconjugate benzothiazoles from protected carbohydrates …

One-pot synthesis of glycosyl-β-azido ester via diazotransfer reaction toward access of glycosyl-β-triazolyl ester

A Mishra, VK Tiwari - The Journal of Organic Chemistry, 2015 - ACS Publications
A concise and efficacious one-pot protocol for the synthesis of novel glycosyl-β-azido ester 3
from glycosyl olefinic ester 1 under mild conditions has been devised. The β-aminoester …

Click chemistry inspired highly facile synthesis of triazolyl ethisterone glycoconjugates

D Kumar, KB Mishra, BB Mishra, S Mondal, VK Tiwari - Steroids, 2014 - Elsevier
Numerous deoxy-azido sugars 3 were prepared by the reaction of tosyl/bromo sugars with
NaN 3 in dry DMF under heating condition. The 1, 3-dipolar cycloaddition of deoxy-azido …

Thermodynamically controlled regioselective glycosylation of fully unprotected sugars through bis (boronate) intermediates

E Kaji, D Yamamoto, Y Shirai, K Ishige… - European Journal of …, 2014 - Wiley Online Library
Fully unprotected d‐glucose, d‐mannose, and d‐fructose were regioselectively glycosylated
with several phenylthioglycosides to afford glycosyl‐β (1→ 6)‐α/β‐d‐glucopyranose …

Regioselective and stereoselective benzylidene installation and one-pot protection of D-mannose

PS Patil, CC Lee, YW Huang, MML Zulueta… - Organic & biomolecular …, 2013 - pubs.rsc.org
Oligosaccharide syntheses are an important source of well-defined sugar constructs
particularly needed for the evaluation of structure–activity relationships. The chemical …

Regioselective facile synthesis of novel isoxazole-linked glycoconjugates

A Mishra, BB Mishra, VK Tiwari - RSC Advances, 2015 - pubs.rsc.org
A concise and efficacious protocol for the regioselective synthesis of novel 3, 5-disubstituted
isoxazole-linked glycoconjugates (4, 7 and 9) via a 1, 3-dipolar cycloaddition reaction …

Deuterium-isotope study on the reductive ring opening of benzylidene acetals

IC Lee, MML Zulueta, CR Shie, SD Arco… - Organic & Biomolecular …, 2011 - pubs.rsc.org
Specific deuterated reference compounds were prepared to probe the stereoselectivity of
the reductive ring opening of carbohydrate-based benzylidene-type acetals. AlD3 revealed …

2.8 Chiral pool synthesis: chiral pool syntheses starting from carbohydrates

N Chida, T Sato - Synthetic Methods I-Chiral Pool and …, 2012 - keio.elsevierpure.com
抄録 Chiral pool synthesis is one of the most effective methods for the preparation of
optically active compounds. This chapter focuses on the synthesis of biologically active …

Introducing Oxo-Phenylacetyl (OPAc) as a Protecting Group for Carbohydrates

A Kumar, V Gannedi, SA Rather… - The Journal of …, 2019 - ACS Publications
A series of oxo-phenylacetyl (OPAc)-protected saccharides, with divergent base sensitivity
profiles against benzoyl (Bz) and acetyl (Ac) were synthesized, and KHSO5/AcCl in …