[HTML][HTML] Multifunctionality of luminescent molecular nanomagnets based on lanthanide complexes

R Jankowski, M Wyczesany, S Chorazy - Chemical Communications, 2023 - pubs.rsc.org
Multifunctional materials, which exhibit diverse physical properties, are candidates for the
new generation of smart devices that realize many tasks simultaneously. Particular attention …

Optical phenomena in molecule-based magnetic materials

JJ Zakrzewski, M Liberka, J Wang, S Chorazy… - Chemical …, 2024 - ACS Publications
Since the last century, we have witnessed the development of molecular magnetism which
deals with magnetic materials based on molecular species, ie, organic radicals and metal …

Luminescence thermometry and field induced slow magnetic relaxation based on a near infrared emissive heterometallic complex

K Karachousos-Spiliotakopoulos, V Tangoulis… - Dalton …, 2022 - pubs.rsc.org
The 1: 1: 1 reaction of YbCl3· 6H2O, K3 [Co (CN) 6] and bpyO2 in H2O has provided access
to a complex with formula [YbCo (CN) 6 (bpyO2) 2 (H2O) 3]· 4H2O (1) in a very good yield …

Slow magnetic relaxation in Nd (iii) and Sm (iii) complexes formed in three-dimensional lanthanide-dicyanidometallate (i) frameworks exhibiting luminescent …

K Kumar, G Li, O Stefanczyk, S Chorazy… - Journal of Materials …, 2023 - pubs.rsc.org
Coordination network-based magnets composed of uncommon Kramers ions (Nd (III) and
Sm (III)) exhibit emissive properties and may realize diverse magneto-optical applications …

Tuning of Ratiometric Optical Thermometry in the Family of Magnetic {Nd1–xIIIYbIIIx[Cu2I(CN)5]} Frameworks Showing the Large SHG Response

Y Xin, K Kumar, JJ Zakrzewski, S Chorazy… - The Journal of …, 2023 - ACS Publications
Three-dimensional (3-D) coordination networks provide a stable framework preferable to
designing materials with tunable properties by various chemical modifications, such as …

Emissive lanthanide dicyanoaurate coordination polymers with 2, 2′-bipyridine dioxide antenna groups and their hydration states

ML Brown, TE Karpiuk, DB Leznoff - CrystEngComm, 2023 - pubs.rsc.org
A series of lanthanide dicyanoaurate coordination polymers with 2, 2′-bipyridine dioxide
(OOBipy) has been created with the formula Ln (OOBipy) 2 (H2O) x [Au (CN) 2] 3· yEtOH …

Ratiometric and Colorimetric Optical Thermometers Using Emissive Dimeric and Trimeric {[Au(SCN)2]}n Moieties Generated in df Heterometallic Assemblies

K Kumar, O Stefanczyk, S Chorazy… - Angewandte Chemie …, 2022 - Wiley Online Library
Gold complexes can generate excimers ([Au2]→[Au2]*) and exciplexes ([Au3]→[Au3]*) with
light excitation. Four GdIII and YIII complexes were assembled with dimeric {[Au (SCN) 2]−} 2 …

Thermochromic and magnetic properties in a 2D manganese (II) coordination polymer:[MnCl2 (bpyO2)] n

C Gao, X Zhang, W Liang, S Zhou, R Zhang… - Inorganic Chemistry …, 2023 - Elsevier
In this work, the synthesis, characterization, and thermochromic properties of a manganese
(II) coordination polymer [MnCl 2 (bpyO 2)](1) were described. The single-crystal X-ray …

Synergy of Experiment and Broadened Exploration of Ab Initio Calculations for Understanding of Lanthanide–Pentacyanidocobaltate Molecular Nanomagnets and …

M Zychowicz, H Dzielak, J Rzepiela… - Inorganic …, 2024 - ACS Publications
We present a synergistic experimental–theoretical methodology for the investigation of
lanthanide-based single-molecule magnets (SMMs), demonstrated using the example of …

Governing efficiency and thermoresponsivity of luminescence in dirhenium (V) molecules by a highly tunable emission mechanism

M Liberka, M Zychowicz, L Vasseur, J Hooper… - Inorganic Chemistry …, 2024 - pubs.rsc.org
The search for strategies that can create photoluminescent (PL) materials linking high
emission efficiency with sensitivity to external stimuli is important for applications in light …