Traceable characterization of nanomaterials by x-ray spectrometry using calibrated instrumentation

B Beckhoff - Nanomaterials, 2022 - mdpi.com
Traceable characterization methods allow for the accurate correlation of the functionality or
toxicity of nanomaterials with their underlaying chemical, structural or physical material …

Ab Initio Prediction of Excited-State and Polaron Effects in Transient XUV Measurements of α-Fe2O3

IM Klein, H Liu, D Nimlos, A Krotz… - Journal of the American …, 2022 - ACS Publications
Transient X-ray and extreme ultraviolet (XUV) spectroscopies have become invaluable tools
for studying photoexcited dynamics due to their sensitivity to carrier occupations and local …

Probing sulfur chemical and electronic structure with experimental observation and quantitative theoretical prediction of Kα and valence-to-core Kβ X-ray emission …

WM Holden, EP Jahrman, N Govind… - The Journal of Physical …, 2020 - ACS Publications
An extensive experimental and theoretical study of the Kα and Kβ high-resolution X-ray
emission spectroscopy (XES) of sulfur-bearing systems is presented. This study …

Sensitivity of the Kβ″ X-ray Emission Line to Coordination Changes in GeO2 and TiO2

G Spiekermann, CJ Sahle, J Niskanen… - The Journal of …, 2023 - ACS Publications
The hard X-ray Kβ ″emission line shows sensitivity with respect to a wide range of cation–
ligand coordination, which we investigate in the cases of GeO2 and TiO2 on the basis of ab …

Titanium and titanium oxides at the K-and L-edges: comparing theoretical calculations to X-ray absorption and X-ray emission measurements

K Bzheumikhova, J Vinson… - Journal of Analytical …, 2023 - pubs.rsc.org
Using well-calibrated experimental data we demonstrate the applicability of theoretical X-ray
absorption spectroscopy (XAS) as well as X-ray emission spectroscopy (XES) calculations …

Valence‐to‐core X‐ray emission spectroscopy of titanium compounds using energy dispersive detectors

L Miaja‐Avila, GC O'Neil, YI Joe, KM Morgan… - X‐Ray …, 2021 - Wiley Online Library
X‐ray emission spectroscopy (XES) of transition metal compounds is a powerful tool for
investigating the spin and oxidation state of the metal centers. Valence‐to‐core (vtc) XES is …

Ab Initio Calculations of XUV Ground and Excited States for First-Row Transition Metal Oxides

IM Klein, A Krotz, W Lee, JM Michelsen… - The Journal of …, 2023 - ACS Publications
Transient X-ray spectroscopies have become ubiquitous in studying photoexcited dynamics
in solar energy materials due to their sensitivity to carrier occupations and local chemical or …

Speciation of iron sulfide compounds by means of X-ray emission spectroscopy using a compact full-cylinder von Hamos spectrometer

M Wansleben, J Vinson, A Wählisch… - Journal of analytical …, 2020 - pubs.rsc.org
We present experimental and theoretical X-ray emission spectroscopy (XES) data of the Fe
Kβ line for iron (II) sulfide (FeS) and iron (II) disulfide (FeS2). In comparison to X-ray …

Near-edge x-ray absorption and emission of cyanates and thiocyanates

K Bzheumikhova, J Vinson, R Unterumsberger… - Physical Review B, 2022 - APS
The comparability and reliability of the analysis of the electronic structure of selected
cyanates and thiocyanates at the nitrogen K edge based on BSE calculations have been …

Chemical sensitivity of the Kα X-ray emission of Ti and Cr compounds induced by 2 MeV protons

S Fazinić, IB Mihalić, M Kavčič, M Petric - Spectrochimica Acta Part B …, 2022 - Elsevier
Kα x-ray emission induced by 2 MeV protons in thick Ti metal, TiO, Ti 2 O 3, TiO 2, MgTiO 3,
FeTiO 3, TiC, TiN, TiB 2, Cr metal, Cr 2 O 3, CrO 2, CrO 3, K 2 Cr 2 O 7 targets was …