The mechanism of water oxidation: from electrolysis via homogeneous to biological catalysis

H Dau, C Limberg, T Reier, M Risch, S Roggan… - …, 2010 - Wiley Online Library
Striving for new solar fuels, the water oxidation reaction currently is considered to be a
bottleneck, hampering progress in the development of applicable technologies for the …

Photosynthetic energy conversion: natural and artificial

J Barber - Chemical Society Reviews, 2009 - pubs.rsc.org
Photosystem II (PSII) is the water splitting enzyme of photosynthesis. Its appearance during
evolution dramatically changed the chemical composition of our planet and set in motion an …

Proton-coupled electron transfer

MHV Huynh, TJ Meyer - Chemical Reviews, 2007 - ACS Publications
At the core of many important energy conversion processes in chemistry and biology are
oxidation-reduction reactions in which both electrons and protons are transferred. An …

Water-splitting chemistry of photosystem II

JP McEvoy, GW Brudvig - Chemical reviews, 2006 - ACS Publications
Life on earth is almost entirely solar-powered. We can get some idea of the enormous
quantity of energy received from the sun by noting that during daylight hours, the sun …

From natural to artificial photosynthesis

J Barber, PD Tran - Journal of The Royal Society …, 2013 - royalsocietypublishing.org
Demand for energy is projected to increase at least twofold by mid-century relative to the
present global consumption because of predicted population and economic growth. This …

Molecular catalysis of electrochemical reactions. Mechanistic aspects

JM Savéant - Chemical Reviews, 2008 - ACS Publications
Electrochemical reactions often require an important overpotential1 to proceed at an
appreciable rate. This is particularly true when the reaction does not merely consist of an …

Missing pieces in the puzzle of biological water oxidation

DA Pantazis - ACS Catalysis, 2018 - ACS Publications
The sunlight-powered oxidation of water by photosystem II (PSII) of algae, plants, and
cyanobacteria underpins the energy conversion processes that sustain most life on our …

Chemical approaches to artificial photosynthesis. 2

JH Alstrum-Acevedo, MK Brennaman… - Inorganic …, 2005 - ACS Publications
The goal of artificial photosynthesis is to use the energy of the sun to make high-energy
chemicals for energy production. One approach, described here, is to use light absorption …

IMP dehydrogenase: structure, mechanism, and inhibition

L Hedstrom - Chemical reviews, 2009 - ACS Publications
George Weber was among the first to recognize that extensive metabolic changes must
underlie the unbridled proliferation of cancer cells. 1 His molecular correlation hypothesis …

The possible role of proton‐coupled electron transfer (PCET) in water oxidation by photosystem II

TJ Meyer, MHV Huynh, HH Thorp - … Chemie International Edition, 2007 - Wiley Online Library
All higher life forms use oxygen and respiration as their primary energy source. The oxygen
comes from water by solar‐energy conversion in photosynthetic membranes. In green …