This Review compiles the evolution, mechanistic understanding, and more recent advances
in enantioselective Pd-catalyzed allylic substitution and decarboxylative and oxidative allylic …

In this review, we summarize the origin and advancements of iridium-catalyzed asymmetric
allylic substitution reactions during the past two decades. Since the first report in 1997, Ir …

Conspectus The catalytic, asymmetric synthesis of complex molecules has been a core
focus of our research program for some time because developments in the area can have an …

The construction of acyclic, non‐adjacent 1, 3‐stereogenic centers, prevalent motifs in drugs
and bioactive molecules, has been a long‐standing synthetic challenge due to acyclic …

A stereodivergent Pd/Cu catalyst system has been developed for the unprecedented
dynamic kinetic asymmetric transformation (DyKAT) of racemic unsymmetrical 1, 3 …

Although much effort has been spent on the enantioselective synthesis of tertiary alkyl
fluorides, the synthesis of compounds containing such a stereogenic center within an array …

Asymmetric cross‐couplings based on 1, 2‐carbon migration from B‐ate complexes have
been developed efficiently to access valuable organoboronates. However, enantioselective …

Enantioselective allylic substitution is one of the most important and reliable reactions for the
synthesis of chiral building blocks. While various transition metal catalysts have been …

The diastereo‐and enantioselective construction of vicinal all‐carbon quaternary
stereocenters is a formidable task. We here report a synergistic bimetallic catalysis via a …

The stereodivergent iridium‐catalyzed allylic alkylation and fluorination of acyclic ketones is
described. α‐Pyridyl‐α‐fluoroketones with vicinal tertiary and quaternary stereocenters were …