Unfolding the chemistry of FOX-7: Unique energetic material and precursor with numerous possibilities
FOX-7 demonstrates a fascinating explosophoric motif with a unique combination of
detonation performance and stability. Unlike classical explosives, such as TNT, TATB, and …
detonation performance and stability. Unlike classical explosives, such as TNT, TATB, and …
Molecular theory of detonation initiation: insight from first principles modeling of the decomposition mechanisms of organic nitro energetic materials
RV Tsyshevsky, O Sharia, MM Kuklja - Molecules, 2016 - mdpi.com
This review presents a concept, which assumes that thermal decomposition processes play
a major role in defining the sensitivity of organic energetic materials to detonation initiation …
a major role in defining the sensitivity of organic energetic materials to detonation initiation …
Pressure DSC for energetic materials. Part 2. Switching between evaporation and thermal decomposition of 3, 5-dinitropyrazole
MV Gorn, KA Monogarov, IL Dalinger, IN Melnikov… - Thermochimica …, 2020 - Elsevier
Differential scanning calorimetry at an elevated external pressure (Pressure DSC) allows for
shifting the vaporization of a sample to higher temperatures, thus often facilitating the direct …
shifting the vaporization of a sample to higher temperatures, thus often facilitating the direct …
Review on the Reactivity of 1, 1‐Diamino‐2, 2‐dinitroethylene (FOX‐7)
Y Zhang, Q Sun, K Xu, J Song… - Propellants, Explosives …, 2016 - Wiley Online Library
Diamino‐2, 2‐dinitroethylene (FOX‐7) is a novel high‐energy insensitive material with good
thermal stability and low sensitivity, and exhibits excellent application performance in the …
thermal stability and low sensitivity, and exhibits excellent application performance in the …
Searching for low-sensitivity cast-melt high-energy-density materials: Synthesis, characterization, and decomposition kinetics of 3, 4-bis (4-nitro-1, 2, 5-oxadiazol-3-yl) …
R Tsyshevsky, P Pagoria, M Zhang… - The Journal of …, 2015 - ACS Publications
The most comprehensive approach to analyze and characterize energetic materials is
suggested and applied to enable rational, rigorous design of novel materials and targeted …
suggested and applied to enable rational, rigorous design of novel materials and targeted …
Early events when heating 1, 1-diamino-2, 2-dinitroethylene: Self-consistent charge density-functional tight-binding molecular dynamics simulations
H Jiang, Q Jiao, C Zhang - The Journal of Physical Chemistry C, 2018 - ACS Publications
A self-consistent charge density-functional tight-binding method combined with molecular
dynamics (MD) simulations and static density functional theory (DFT) calculations is …
dynamics (MD) simulations and static density functional theory (DFT) calculations is …
Reversible intramolecular hydrogen transfer: a completely new mechanism for low impact sensitivity of energetic materials
Y Xiong, Y Ma, X He, X Xue, C Zhang - Physical Chemistry Chemical …, 2019 - pubs.rsc.org
The intramolecular H transfer of energetic NO2-compounds has been recognized as a
possible primary step in triggering molecular decomposition for a long time. Nevertheless …
possible primary step in triggering molecular decomposition for a long time. Nevertheless …
Straightforward access to the nitric oxide donor Azasydnone scaffold by cascade reactions of amines
A novel one‐pot cascade method for the assembly of valuable NO‐donor azasydnone
scaffold has been developed. The construction strategy involves a diazotization/azo …
scaffold has been developed. The construction strategy involves a diazotization/azo …
Accurate thermochemistry of novel energetic fused tricyclic 1, 2, 3, 4-tetrazine nitro derivatives from local coupled cluster methods
VG Kiselev, CF Goldsmith - The Journal of Physical Chemistry A, 2019 - ACS Publications
Highly accurate theoretical values of formation enthalpies and bond energies are crucial for
reliable predictions of performance and detonation-related phenomena of energetic …
reliable predictions of performance and detonation-related phenomena of energetic …
Ultraviolet-Initiated Decomposition of Solid 1, 1-Diamino-2, 2-Dinitroethylene (FOX-7)
AM Turner, JH Marks, JT Lechner… - The Journal of …, 2023 - ACS Publications
FOX-7 (1, 1-diamino-2, 2-dinitroethylene) was photolyzed with 202 nm photons to probe
reaction energies, leading to the decomposition of this energetic material and to compare …
reaction energies, leading to the decomposition of this energetic material and to compare …