Synthetic Strategies for Rare Cannabinoids Derived from Cannabis sativa
Efficient syntheses of eight key cannabinoids were established and optimized. Predominant
cannabinoids such as cannabigerol (CBG-C5) and cannabidiol (CBD-C5) were prepared …
cannabinoids such as cannabigerol (CBG-C5) and cannabidiol (CBD-C5) were prepared …
Iodine-catalyzed direct C–H alkenylation of azaheterocycle N-oxides with alkenes
Z Zhang, C Pi, H Tong, X Cui, Y Wu - Organic letters, 2017 - ACS Publications
An efficient and regioselective alkenylation of azaheterocycle N-oxides with alkenes
catalyzed by iodine under metal-and external oxidant-free reaction conditions has been …
catalyzed by iodine under metal-and external oxidant-free reaction conditions has been …
Diterpenoids of terrestrial origin
JR Hanson - Natural product reports, 2017 - pubs.rsc.org
Covering: January to December, 2016 previous review Nat. Prod. Rep., 2016, 33, 1227–
1238 This review covers the isolation and chemistry of diterpenoids from terrestrial as …
1238 This review covers the isolation and chemistry of diterpenoids from terrestrial as …
Modular and selective synthesis of pyrazolo-azepino-centred polycyclic aromatic and non-aromatic architectures
T Chen, JT Ma, XL Chen, Y Zhou, ZC Yu… - Organic Chemistry …, 2023 - pubs.rsc.org
The pyrazolo-azepino-centred polyheterocyclic fused system is a privileged scaffold, but it
lacks an effective synthetic approach, with modular synthesis being even more scarce …
lacks an effective synthetic approach, with modular synthesis being even more scarce …
One-pot total synthesis of cannabinol via iodine-mediated deconstructive annulation
The thermal degradation of cannabichromene (CBC, 3) is dominated by cationic reactions
and not by the pericyclic rearrangements observed in model compounds. The rationalization …
and not by the pericyclic rearrangements observed in model compounds. The rationalization …
p‐Menthadienes as Biorenewable Feedstocks for a Monoterpene‐Based Biorefinery
JD Tibbetts, SD Bull - Advanced Sustainable Systems, 2021 - Wiley Online Library
A terpene‐based biorefinery is described that uses crude sulfate turpentine (CST) and gum
turpentine (GT) to produce mixtures of p‐menthadienes (p‐MeDs) as biorenewable terpene …
turpentine (GT) to produce mixtures of p‐menthadienes (p‐MeDs) as biorenewable terpene …
Hydroarylation of Alkenes by Protonation/Friedel–Crafts Trapping: HFIP-Mediated Access to Per-aryl Quaternary Stereocenters
CDT Nielsen, AJP White, D Sale, J Bures… - The Journal of …, 2019 - ACS Publications
Upon treatment with a combination of HFIP and an organic sulfonic acid, alkenes behave as
Brønsted bases and protonate to give carbocations which can be trapped by electron-rich …
Brønsted bases and protonate to give carbocations which can be trapped by electron-rich …
Iodine-Promoted Aromatization of p-Menthane-Type Phytocannabinoids
F Pollastro, D Caprioglio, P Marotta… - Journal of natural …, 2017 - ACS Publications
Treatment with iodine cleanly converts various p-menthane-type phytocannabinoids and
their carboxylated precursors into cannabinol (CBN, 1a). The reaction is superior to …
their carboxylated precursors into cannabinol (CBN, 1a). The reaction is superior to …
Gold-Catalyzed Oxidation Terminal Alkyne: An Approach to Synthesize Substituted Dihydronaphthalen-2(1H)-ones and Phenanthrenols
HB Ling, ZS Chen, F Yang, B Xu… - The Journal of organic …, 2017 - ACS Publications
A facile gold-catalyzed oxidation terminal alkynes to synthesize substituted
dihydronaphthalen-2 (1 H)-ones 3 and phenanthrenols 5 was realized. Various useful …
dihydronaphthalen-2 (1 H)-ones 3 and phenanthrenols 5 was realized. Various useful …
Novel insect antifeedant and ixodicidal nootkatone derivatives
A Galisteo Pretel, H Pérez del Pulgar, AS Olmeda… - Biomolecules, 2019 - mdpi.com
Naturally occurring nootkatone, with reported insecticidal and acaricidal properties, has
been used as a lead to generate molecular diversity and, consequently, new insect …
been used as a lead to generate molecular diversity and, consequently, new insect …