How the structural deviations on the backbone of conjugated polymers influence their optoelectronic properties and photovoltaic performance

CL Chochos, SA Choulis - Progress in polymer science, 2011 - Elsevier
The design of novel conjugated polymers with appropriate frontier orbital energy levels, low
band gap (LBG) and suitable carrier transport properties are needed to improve the power …

2, 1, 3‐Benzothiadiazole and derivatives: synthesis, properties, reactions, and applications in light technology of small molecules

BAD Neto, AAM Lapis… - European Journal of …, 2013 - Wiley Online Library
Abstract 2, 1, 3‐Benzothiadiazole (BTD) is one of the most important nuclei used in the
chemistry of photoluminescent compounds and applicable for light technology. The …

Rational design of high performance conjugated polymers for organic solar cells

H Zhou, L Yang, W You - Macromolecules, 2012 - ACS Publications
The research on the polymer-based solar cells (PSCs) has attracted an increasing amount
of attention in recent years because PSCs pose potential advantages over mainstream …

Fluorinated copolymer PCPDTBT with enhanced open-circuit voltage and reduced recombination for highly efficient polymer solar cells

S Albrecht, S Janietz, W Schindler… - Journal of the …, 2012 - ACS Publications
A novel fluorinated copolymer (F-PCPDTBT) is introduced and shown to exhibit significantly
higher power conversion efficiency in bulk heterojunction solar cells with PC70BM …

Atomistic band gap engineering in donor–acceptor polymers

GL Gibson, TM McCormick… - Journal of the American …, 2012 - ACS Publications
We have synthesized a series of cyclopentadithiophene–benzochalcogenodiazole donor–
acceptor (D–A) copolymers, wherein a single atom in the benzochalcogenodiazole unit is …

Photochemical stability of π-conjugated polymers for polymer solar cells: a rule of thumb

M Manceau, E Bundgaard, JE Carlé… - Journal of Materials …, 2011 - pubs.rsc.org
A comparative photochemical stability study of a wide range of π-conjugated polymers
relevant to polymer solar cells is presented. The behavior of each material has been …

Donor–acceptor semiconducting polymers for organic solar cells

RS Kularatne, HD Magurudeniya… - Journal of Polymer …, 2013 - Wiley Online Library
This review describes the synthesis and photovoltaic performance of donor–acceptor (D–A)
semiconducting polymers that have been reported during the last decade. 9, 9‐Dialkyl‐2, 7 …

A quantum-chemical perspective into low optical-gap polymers for highly-efficient organic solar cells

C Risko, MD McGehee, JL Brédas - Chemical Science, 2011 - pubs.rsc.org
The recent and rapid enhancement in power conversion efficiencies of organic-based, bulk-
heterojunction solar cells has been a consequence of both improved materials design and …

Lewis acid adducts of narrow band gap conjugated polymers

GC Welch, GC Bazan - Journal of the American Chemical Society, 2011 - ACS Publications
We report on the interaction of Lewis acids with narrow band gap conjugated copolymers
containing donor and acceptor units. Examination of the widely used poly [(4, 4-bis (2 …

Optimizing the performance of conjugated polymers in organic photovoltaic cells by traversing group 16

M Jeffries-EL, BM Kobilka, BJ Hale - Macromolecules, 2014 - ACS Publications
Conjugated polymers are organic semiconductors that have emerged over the past few
decades as promising alternatives to inorganic semiconductors for use in a range of …