Rare-earth metal complexes as catalysts for ring-opening polymerization of cyclic esters

DM Lyubov, AO Tolpygin, AA Trifonov - Coordination Chemistry Reviews, 2019 - Elsevier
Rare-earth metal complexes as catalysts for ring-opening polymerization of cyclic esters -
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Progress of ring-opening polymerization of cyclic esters catalyzed by iron compounds

Y Wang, X Wang, W Zhang, WH Sun - Organometallics, 2023 - ACS Publications
Aliphatic polyesters such as polylactide (PLA) and polycaprolactone (PCL) have attracted
much attention due to their prominent features of environmentally friendly materials with …

Uniform Core–Shell Microspheres of SiO2@MOF for CO2 Cycloaddition Reactions

CY Tsai, YH Chen, S Lee, CH Lin, CH Chang… - Inorganic …, 2022 - ACS Publications
A SiO2@ MOF core–shell microsphere for environmentally friendly applications was
introduced in this study. Several types of metal–organic framework core–shell microspheres …

Recent advances in the electrochemical functionalization of N-heterocycles

MK Yadav, S Chowdhury - Organic & Biomolecular Chemistry, 2025 - pubs.rsc.org
Nitrogen-containing heterocyclic cores are of immense importance due to their high
abundance in naturally occurring or synthetic molecules having wide applications in …

Flexible NHC-aryloxido aluminum complex and its zwitterionic imidazolium aluminate precursor in ring-opening polymerization of ε-caprolactone

S Goswami, P Mandal, S Sarkar, M Mukherjee… - Dalton …, 2024 - pubs.rsc.org
Anionic donor-functionalized NHC (N-heterocyclic carbene) complexes of Al are rare. We
report one such case here, an NHC-aryloxido AlMe2 complex [Al (L) Me2](2), following a …

Phenoxy-imine supported hexacoordinate tetravalent titanium compounds: Synthesis, characterization and catalytic applications for ROP and ROCOP reactions

S Sarkar, SS Roy, S Krishnaswamy… - European Polymer …, 2024 - Elsevier
Two series of tetravalent titanium catalysts, which include bis (isopropoxide)(1–5) and
dichloro-(6–7) compounds, are reported. The compounds are supported by phenoxy-imine …

Alternating copolymerization of epoxides with carbon dioxide or cyclic anhydrides using bimetallic nickel and cobalt catalysts: Preparation of hydrophilic nanofibers …

CH Chang, CY Tsai, WJ Lin, YC Su, HJ Chuang… - Polymer, 2018 - Elsevier
A series of di-nuclear metal acetate complexes 1–6 incorporated by nitrogen heterocycle-
containing salen-type ligands have been synthesized, structurally characterized and …

Ring-Opening Polymerization of ε-Caprolactone by Using Aluminum Complexes Bearing Aryl Thioether Phenolates: Labile Thioether Chelation

SR Kosuru, YL Chang, PY Chen, W Lee… - Inorganic …, 2022 - ACS Publications
In this study, aluminum complexes bearing ferrocene-based and arylthiomethylphenolate
ligands were synthesized, and their catalytic activity for ε-caprolactone (CL) polymerization …

High-Activity and High-Selectivity Air-Stable Nickel and Copper Complexes for Copolymerization of Epoxides with Anhydrides

ML Lin, CY Tsai - Inorganic Chemistry, 2023 - ACS Publications
Ring-opening copolymerization (ROCOP) of epoxides with anhydrides presents a highly
promising pathway for the synthesis of diverse polyester copolymers. This process involves …

Copolymerization of carbon dioxide with epoxides catalyzed by structurally well-characterized dinickel bis (benzotriazole iminophenolate) complexes: influence of …

LS Huang, CY Tsai, HJ Chuang, BT Ko - Inorganic Chemistry, 2017 - ACS Publications
A series of structurally well-defined dinickel carboxylate complexes based on the RBiIBTP
derivatives [RBiIBTP= bis (benzotriazole iminophenolate), where R= 3C for the propyl …