Modeling the rheology of polymer melts and solutions

RG Larson, PS Desai - Annual Review of Fluid Mechanics, 2015 - annualreviews.org
We review constitutive modeling of solutions and melts of linear polymers, focusing on
changes in rheological behavior in shear and extensional flow as the concentration …

Shear and extensional rheology of polystyrene melts and solutions with the same number of entanglements

S Costanzo, Q Huang, G Ianniruberto… - …, 2016 - ACS Publications
We investigate the nonlinear shear and uniaxial extensional rheology of entangled
polystyrene (PS) melts and solutions having the same number Z of entanglements, hence …

[HTML][HTML] The rheology of aqueous solutions of ethyl hydroxy-ethyl cellulose (EHEC) and its hydrophobically modified analogue (hmEHEC): extensional flow response …

V Sharma, SJ Haward, J Serdy, B Keshavarz… - Soft matter, 2015 - pubs.rsc.org
Cellulose derivatives containing associating hydrophobic groups along their hydrophilic
backbone are used as rheology modifiers in the formulation of water-based spray paints …

Flexibility, extensibility, and ratio of Kuhn length to packing length govern the pinching dynamics, coil-stretch transition, and rheology of polymer solutions

J Dinic, V Sharma - Macromolecules, 2020 - ACS Publications
We elucidate the influence of chemical structure on macromolecular hydrodynamics,
rheological response, and pinching dynamics underlying drop formation/liquid transfer using …

Evaporation and rheology chart the processability map for centrifugal force spinning

J Merchiers, CDV Martínez Narváez, C Slykas… - …, 2021 - ACS Publications
We show that poly (ethylene oxide)(PEO) solutions formulated using solvent mixtures of
acetonitrile (AcN) and water can be centrifugally spun into fibers. We find that spinnability …

Entanglement reduction and anisotropic chain and primitive path conformations in polymer melts under thin film and cylindrical confinement

DM Sussman, WS Tung, KI Winey, KS Schweizer… - …, 2014 - ACS Publications
We simulate and theoretically analyze the properties of entangled polymer melts confined in
thin film and cylindrical geometries. Macromolecular-scale conformational changes are …

Solvent properties influence the rheology and pinching dynamics of polyelectrolyte solutions: Thickening the pot with glycerol and cellulose gum

LN Jimenez, CDV Martínez Narváez, V Sharma - Macromolecules, 2022 - ACS Publications
Charge-bearing groups that ionize in solution influence the macromolecular conformations,
interactions, and dynamics of polyelectrolytes. The rich and complex shear rheological …

[HTML][HTML] DNA as a model for probing polymer entanglements: Circular polymers and non-classical dynamics

K Regan, S Ricketts, RM Robertson-Anderson - Polymers, 2016 - mdpi.com
Double-stranded DNA offers a robust platform for investigating fundamental questions
regarding the dynamics of entangled polymer solutions. The exceptional monodispersity …

Nonlinear Elongational Rheology of Unentangled Polystyrene and Poly(p-tert-butylstyrene) Melts

Y Matsumiya, H Watanabe, Y Masubuchi… - …, 2018 - ACS Publications
Nonlinear rheological behavior under uniaxial elongation was examined for unentangled
melts of polystyrene (PS27; molecular weight M= 27k) and poly (p-tert-butylstyrene)(PtBS53; …

Rheology and pinching dynamics of associative polysaccharide solutions

CDV Martínez Narváez, J Dinic, X Lu, C Wang… - …, 2021 - ACS Publications
Associative polysaccharides, decorated by multiple but short, side-chain hydrophobic
stickers (typically 6–20 carbon long) that associate in solution, are used as thickeners for an …