Modeling the rheology of polymer melts and solutions
We review constitutive modeling of solutions and melts of linear polymers, focusing on
changes in rheological behavior in shear and extensional flow as the concentration …
changes in rheological behavior in shear and extensional flow as the concentration …
Shear and extensional rheology of polystyrene melts and solutions with the same number of entanglements
S Costanzo, Q Huang, G Ianniruberto… - …, 2016 - ACS Publications
We investigate the nonlinear shear and uniaxial extensional rheology of entangled
polystyrene (PS) melts and solutions having the same number Z of entanglements, hence …
polystyrene (PS) melts and solutions having the same number Z of entanglements, hence …
[HTML][HTML] The rheology of aqueous solutions of ethyl hydroxy-ethyl cellulose (EHEC) and its hydrophobically modified analogue (hmEHEC): extensional flow response …
Cellulose derivatives containing associating hydrophobic groups along their hydrophilic
backbone are used as rheology modifiers in the formulation of water-based spray paints …
backbone are used as rheology modifiers in the formulation of water-based spray paints …
Flexibility, extensibility, and ratio of Kuhn length to packing length govern the pinching dynamics, coil-stretch transition, and rheology of polymer solutions
We elucidate the influence of chemical structure on macromolecular hydrodynamics,
rheological response, and pinching dynamics underlying drop formation/liquid transfer using …
rheological response, and pinching dynamics underlying drop formation/liquid transfer using …
Evaporation and rheology chart the processability map for centrifugal force spinning
J Merchiers, CDV Martínez Narváez, C Slykas… - …, 2021 - ACS Publications
We show that poly (ethylene oxide)(PEO) solutions formulated using solvent mixtures of
acetonitrile (AcN) and water can be centrifugally spun into fibers. We find that spinnability …
acetonitrile (AcN) and water can be centrifugally spun into fibers. We find that spinnability …
Entanglement reduction and anisotropic chain and primitive path conformations in polymer melts under thin film and cylindrical confinement
We simulate and theoretically analyze the properties of entangled polymer melts confined in
thin film and cylindrical geometries. Macromolecular-scale conformational changes are …
thin film and cylindrical geometries. Macromolecular-scale conformational changes are …
Solvent properties influence the rheology and pinching dynamics of polyelectrolyte solutions: Thickening the pot with glycerol and cellulose gum
LN Jimenez, CDV Martínez Narváez, V Sharma - Macromolecules, 2022 - ACS Publications
Charge-bearing groups that ionize in solution influence the macromolecular conformations,
interactions, and dynamics of polyelectrolytes. The rich and complex shear rheological …
interactions, and dynamics of polyelectrolytes. The rich and complex shear rheological …
[HTML][HTML] DNA as a model for probing polymer entanglements: Circular polymers and non-classical dynamics
K Regan, S Ricketts, RM Robertson-Anderson - Polymers, 2016 - mdpi.com
Double-stranded DNA offers a robust platform for investigating fundamental questions
regarding the dynamics of entangled polymer solutions. The exceptional monodispersity …
regarding the dynamics of entangled polymer solutions. The exceptional monodispersity …
Nonlinear Elongational Rheology of Unentangled Polystyrene and Poly(p-tert-butylstyrene) Melts
Y Matsumiya, H Watanabe, Y Masubuchi… - …, 2018 - ACS Publications
Nonlinear rheological behavior under uniaxial elongation was examined for unentangled
melts of polystyrene (PS27; molecular weight M= 27k) and poly (p-tert-butylstyrene)(PtBS53; …
melts of polystyrene (PS27; molecular weight M= 27k) and poly (p-tert-butylstyrene)(PtBS53; …
Rheology and pinching dynamics of associative polysaccharide solutions
Associative polysaccharides, decorated by multiple but short, side-chain hydrophobic
stickers (typically 6–20 carbon long) that associate in solution, are used as thickeners for an …
stickers (typically 6–20 carbon long) that associate in solution, are used as thickeners for an …