Metal-organic frameworks as a versatile platform for radionuclide management

K Jin, B Lee, J Park - Coordination chemistry reviews, 2021 - Elsevier
Fuel fission products and fuel production byproducts contain radioactive nuclides such as
129/131 I, 127 Xe, 85 Kr, 235 U, 137 Cs, 90 Sr, 99 Tc, and 79 Se that exist in gaseous, ionic …

Cluster‐Based Crystalline Materials for Iodine Capture

ST Wang, YJ Liu, CY Zhang, F Yang… - … A European Journal, 2023 - Wiley Online Library
The treatment of radioactive iodine in nuclear waste has always been a critical issue of
social concern. The rational design of targeted and efficient capture materials is of great …

Smart metal–organic frameworks with reversible luminescence/magnetic switch behavior for HCl vapor detection

ZH Zhu, Z Ni, HH Zou, G Feng… - Advanced Functional …, 2021 - Wiley Online Library
Smart luminescent metal–organic frameworks (MOFs) demonstrate promising performance
in the detection of toxic gases. The incorporation of twisted or rotary organic ligands with …

Optimizing iodine capture performance by metal-organic framework containing with bipyridine units

X Yang, X Liu, Y Liu, XF Wang, Z Chen… - Frontiers of Chemical …, 2023 - Springer
Radioactive iodine exhibits medical values in radiology, but its excessive emissions can
cause environmental pollution. Thus, the capture of radioiodine poses significant …

A Porphyrin‐Based 3D Metal‐Organic Framework Featuring [Cu8Cl6]10+ Cluster Secondary Building Units: Synthesis, Structure Elucidation, Anion Exchange, and …

CM Zeng, SY Luo, X Wang, FL Cao… - Chemistry–An Asian …, 2024 - Wiley Online Library
Herein, we report a rare example of cationic three‐dimensional (3D) metal‐organic
framework (MOF) of [Cu5Cl3 (TMPP)] Cl5⋅ xSol (denoted as Cu− TMPP; H2TMPP= meso …

A tetranuclear-cluster-based MOF with a low-polarity pore environment for efficient C 2 H 6/C 2 H 4 separation

M Feng, J Li, X Wang, J Wang, D Wang… - Inorganic Chemistry …, 2024 - pubs.rsc.org
Removing trace ethane (C2H6) from ethylene (C2H4) to obtain high-purity C2H4 is of great
industrial significance. However, the construction of C2H6-selective metal–organic …

Highly Efficient I2 Sorption, CO2 Capture, and Catalytic Conversion by Introducing Nitrogen Donor Sites in a Microporous Co(II)-Based Metal–Organic Framework

ZH Guo, YD Zhang, QQ Wang, Y Wang… - Inorganic …, 2022 - ACS Publications
Recently, the development of porous absorbents for efficient CO2 and I2 capture has
attracted considerable attention because of severe global climate change and …

A diamond-like cuprous coordination polymer based on the [Cu 8 I 6] 2+ cluster with multistimuli-responsive luminescence and iodine adsorption behavior

HW Zheng, DD Yang, QF Liang, YP Liu… - Journal of Materials …, 2022 - pubs.rsc.org
Copper (I) iodide-based compounds can exhibit interesting multistimuli-responsive
behaviors and have attracted great interest due to their widespread applications. In this …

Investigation of iodine adsorption based on isomeric polyoxovanadate-based metal–organic cages

QQ Chu, Y Lin, LY Wang, YR Gong, XL Wang, QH Pan… - Polyhedron, 2024 - Elsevier
Three polyoxovanadate-based metal–organic cages,[NH 2 Me 2] 8 {[V 6 O 6 (OMe) 9 (SO 4)]
4 (BPT) 4}·(MeOH) 11 (HNU-85),[NH 2 Me 2] 8 {[V 6 O 6 (OMe) 9 (SO 4)] 4 (BPT) 4}·(MeOH) …

Cu (I)-organic framework as a platform for high-efficiency selective adsorption of methylene blue and reversible iodine uptake

YT Yang, CZ Tu, JY Shi, XL Yang, JJ Liu… - Journal of Solid State …, 2022 - Elsevier
Abstract A Cu (I)-MOF, namely {[Cu (4-PTZ)]·(H 2 O) 0.5} n (1), that contains rhombic
channels with the size of 10.174​ Å​×​ 16.965​ Å has been obtained based on in situ …