A light-triggered, Ni-catalyzed cyanation of aryl triflates was herein reported, which provides
a benign photochemical synthesis of aryl nitriles using 1, 4-dicyanobenzene as the CN …

The radical 1, 4-functionalizations of 1, 3-enynes have emerged as a powerful strategy for
the synthesis of multisubstituted allenes. However, the phosphorus-centered radical-initiated …

Catalytic cleavage of Csingle bondS bonds is an important approach in the construction of
functionalized molecules. Herein, we developed the catalytic synthesis of nitriles from …

Herein we reported a manganese promoted reductive cross‐coupling approach to construct
P‒S bond. This is a practical method for the synthesis of mono‐thiophosphanes, bis …

Nitriles are valuable compounds because they have widespread applications in organic
chemistry. This report details the nickel-catalyzed reductive cyanation of aryl halides and …

Low‐valent chromium catalysts are cheap and less toxic compared to other transition metal
catalysts. Here in, we reported a ligand‐free chromium (III)‐catalyzed manganese reductive …

Unactivated N-alkene-linked indoles were established as general substrates for
cyanomethylation-cyclization cascade reactions with bromoacetonitrile in a photoinduced …

Significance: Nitriles are often used as a key intermediate in many synthetic routes due to
their versatile nature. They can be transformed into a variety of useful functional groups and …