Technological innovations in photochemistry for organic synthesis: flow chemistry, high-throughput experimentation, scale-up, and photoelectrochemistry
L Buglioni, F Raymenants, A Slattery… - Chemical …, 2021 - ACS Publications
Photoinduced chemical transformations have received in recent years a tremendous amount
of attention, providing a plethora of opportunities to synthetic organic chemists. However …
of attention, providing a plethora of opportunities to synthetic organic chemists. However …
Photocatalysis in the life science industry
L Candish, KD Collins, GC Cook, JJ Douglas… - Chemical …, 2021 - ACS Publications
In the pursuit of new pharmaceuticals and agrochemicals, chemists in the life science
industry require access to mild and robust synthetic methodologies to systematically modify …
industry require access to mild and robust synthetic methodologies to systematically modify …
[HTML][HTML] Recent advances in visible light-activated radical coupling reactions triggered by (i) ruthenium,(ii) iridium and (iii) organic photoredox agents
Photoredox chemistry with organic or transition metal agents has been reviewed in earlier
years, but such is the pace of progress that we will overlap very little with earlier …
years, but such is the pace of progress that we will overlap very little with earlier …
Generation of alkyl radicals: from the tyranny of tin to the photon democracy
Alkyl radicals are key intermediates in organic synthesis. Their classic generation from alkyl
halides has a severe drawback due to the employment of toxic tin hydrides to the point that …
halides has a severe drawback due to the employment of toxic tin hydrides to the point that …
Synthetic photoelectrochemistry
Photoredox catalysis (PRC) and synthetic organic electrochemistry (SOE) are often
considered competing technologies in organic synthesis. Their fusion has been largely …
considered competing technologies in organic synthesis. Their fusion has been largely …
Scalability of photochemical reactions in continuous flow mode
K Donnelly, M Baumann - Journal of Flow Chemistry, 2021 - Springer
Continuous flow photochemistry as a field has witnessed an increasing popularity over the
last decade in both academia and industry. Key drivers for this development are safety …
last decade in both academia and industry. Key drivers for this development are safety …
Programmable late-stage functionalization of bridge-substituted bicyclo [1.1. 1] pentane bis-boronates
Modular functionalization enables versatile exploration of chemical space and has been
broadly applied in structure–activity relationship (SAR) studies of aromatic scaffolds during …
broadly applied in structure–activity relationship (SAR) studies of aromatic scaffolds during …
Boron, silicon, nitrogen and sulfur-based contemporary precursors for the generation of alkyl radicals by single electron transfer and their synthetic utilization
V Corcé, C Ollivier, L Fensterbank - Chemical Society Reviews, 2022 - pubs.rsc.org
Recent developments in the use of boron, silicon, nitrogen and sulfur derivatives in single-
electron transfer reactions for the generation of alkyl radicals are described. Photoredox …
electron transfer reactions for the generation of alkyl radicals are described. Photoredox …
The impact of boron hybridisation on photocatalytic processes
A Marotta, CE Adams, JJ Molloy - Angewandte Chemie, 2022 - Wiley Online Library
Recently the fruitful merger of organoboron chemistry and photocatalysis has come to the
forefront of organic synthesis, resulting in the development of new technologies to access …
forefront of organic synthesis, resulting in the development of new technologies to access …
Rapid optimization of photoredox reactions for continuous-flow systems using microscale batch technology
M González-Esguevillas, DF Fernández… - ACS Central …, 2021 - ACS Publications
Photoredox catalysis has emerged as a powerful and versatile platform for the synthesis of
complex molecules. While photocatalysis is already broadly used in small-scale batch …
complex molecules. While photocatalysis is already broadly used in small-scale batch …