Borates: A rich source for optical materials

M Mutailipu, KR Poeppelmeier, S Pan - Chemical Reviews, 2020 - ACS Publications
The primary goal of this review is to present a clear chemical perspective of borates in order
to stimulate and facilitate the discovery of new borate-based optical materials. These …

The Strategy to Improve the Phase Matching Ability in Tetrahedron‐Based Deep‐Ultraviolet Nonlinear Optical Crystals

H Sha, Y Shang, Z Wang, R Su, C He… - Advanced Optical …, 2023 - Wiley Online Library
Nonlinear optical (NLO) crystals that can generate deep‐ultraviolet (DUV) lasers by the
frequency conversion processes play an important role in many basic and frontier research …

Hydroxyfluorooxoborate (NH 4)[C (NH 2) 3][B 3 O 3 F 4 (OH)] for exploring the effects of cation substitution on structure and optical properties

Z Chen, F Li, Z Yang, S Pan, M Mutailipu - Chemical Communications, 2023 - pubs.rsc.org
Cation substitution is a straightforward but effective technique for improving the structure and
properties; however, controlling directed substitution still poses significant difficulties …

Ba6Zn6(B3O6)6(B6O12): Barium Zinc Borate Contains π-Conjugated [B3O6]3– Anions and [B6O12]6– Anion with Edge-Sharing BO4 Tetrahedra

WJ Xie, Z Fang, JG Mao - Inorganic Chemistry, 2022 - ACS Publications
A novel barium zinc borate contains π-conjugated [B3O6] 3–anions and [B6O12] 6–anion
with edge-sharing BO4 tetrahedra, Ba6Zn6 (B3O6) 6 (B6O12), has been successfully …

Cd8(BO3)4SiO4: Metal Cation Inducing the Formation of Isolated [BO3] and [SiO4] Units in Borate Silicate

G Xu, H Li, J Han, X Hou, Z Yang, S Pan - Inorganic Chemistry, 2023 - ACS Publications
The first compound of cadmium–borate silicate Cd8 (BO3) 4SiO4, crystallizing in space
group P 42/n (no. 86), has been successfully synthesized by the conventional high …

LiNa2Ca8B12O24F6Cl and Li1. 2Na2. 8B6O11: A Case of Cation-Induced Birefringence Enhancement via Dimensional Changes of Highly Polymerized [B12O24] …

Z Yan, J Fan, D Chu, Z Yang, J Lu, S Pan… - Inorganic …, 2024 - ACS Publications
Borates, due to their structural chemistry diversity and exceptional performance, are premier
material systems for investigating UV optical crystals. The B–O anionic groups with high …

Recent Progress in Crystalline Borates with Edge-Sharing BO4 Tetrahedra

JJ Li, WF Chen, YZ Lan, JW Cheng - Molecules, 2023 - mdpi.com
Crystalline borates have received great attention due to their various structures and wide
applications. For a long time, the corner-sharing B–O unit is considered a basic rule in …

Finding a Deep‐UV Borate BaZnB4O8 with Edge‐sharing [BO4] Tetrahedra and Strong Optical Anisotropy

J Han, K Liu, L Chen, F Li, Z Yang… - … A European Journal, 2023 - Wiley Online Library
The polarization modulation of deep‐UV light is an important process that incorporates
functionality to selectively respond to light‐mater interaction. Typically, optical anisotropy is …

Bi2[B2(SeO3)6]: A Metal Boroselenite with a Unique Zero-Dimensional [B2(SeO3)6]6– Anionic Group and Large Birefringence

RL Tang, CL Hu, WJ Xie, QM Huang… - Inorganic Chemistry, 2021 - ACS Publications
Explorations of new types of borates are important because of their promising application in
diverse fields. A new bismuth-containing boroselenite, Bi2 [B2 (SeO3) 6], has been obtained …

γ-BaB2O4: High-Pressure High-Temperature Polymorph of Barium Borate with Edge-Sharing BO4 Tetrahedra

TB Bekker, IV Podborodnikov, NE Sagatov… - Inorganic …, 2022 - ACS Publications
The α-and β-modifications of barium metaborate are important functional materials used in
optoelectronic devices. A new theoretically predicted modification of BaB2O4 has been …