Physicochemical concepts of the lithium metal anode in solid-state batteries

T Krauskopf, FH Richter, WG Zeier, J Janek - Chemical reviews, 2020 - ACS Publications
Developing reversible lithium metal anodes with high rate capability is one of the central
aims of current battery research. Lithium metal anodes are not only required for the …

Recent advances in anodic interface engineering for solid-state lithium-metal batteries

C Sun, Y Ruan, W Zha, W Li, M Cai, Z Wen - Materials Horizons, 2020 - pubs.rsc.org
Lithium (Li) metal is recognized as the “Holy Grail” in the energy storage field because of its
high specific capacity and ultralow anodic potential. To realize high-safety and high-energy …

Excellent Stability of Ga-Doped Garnet Electrolyte against Li Metal Anode via Eliminating LiGaO2 Precipitates for Advanced All-Solid-State Batteries

J Li, H Luo, K Liu, J Zhang, H Zhai, X Su… - … Applied Materials & …, 2023 - ACS Publications
Ga-doped garnet-type Li7La3Zr2O12 (Ga-LLZO) ceramics have long been recognized as
ideal electrolyte candidates for all-solid-state lithium batteries (ASSLBs). However, in this …

Revealing Atomic‐Scale Ionic Stability and Transport around Grain Boundaries of Garnet Li7La3Zr2O12 Solid Electrolyte

B Gao, R Jalem, HK Tian… - Advanced Energy …, 2022 - Wiley Online Library
For real applications of all‐solid‐state batteries (ASSBs) to be realized, understanding and
control of the grain boundaries (GBs) are essential. However, the in‐depth insight into the …

Unlocking the chemical space in anti-perovskite conductors by incorporating anion rotation dynamics

C Guan, Y Yang, R Ouyang, H Jing, J Yan, G Li… - Energy Storage …, 2023 - Elsevier
Anti-perovskite compounds have drawn significant research interest as promising next-
generation electrolytes for solid-state batteries, due to the high chemical stability against Li …

[HTML][HTML] Atomistic insight into the dopant impacts at the garnet Li 7 La 3 Zr 2 O 12 solid electrolyte grain boundaries

B Gao, R Jalem, Y Tateyama - Journal of Materials Chemistry A, 2022 - pubs.rsc.org
The garnet-type Li7La3Zr2O12 (LLZO) as one of the most promising solid electrolytes (SEs)
has attracted great research attention owing to its high compatibility with Li metal anodes …

Native Defects and Their Doping Response in the Lithium Solid Electrolyte Li7La3Zr2O12

AG Squires, DO Scanlon, BJ Morgan - Chemistry of Materials, 2019 - ACS Publications
The Li-stuffed garnets Li x M 2 M 3′ O12 are promising Li-ion solid electrolytes with
potential use in solid-state batteries. One strategy for optimizing ionic conductivities in these …

High cycling stability enabled by Li vacancy regulation in Ta-doped garnet-type solid-state electrolyte

Z Qin, Y Xie, X Meng, C Shan, G He, D Qian… - Journal of the European …, 2023 - Elsevier
Ta-doped solid-state electrolyte (SSE) is employed to reveal Li vacancy regulation process
and densification mechanism through thermodynamic analysis. The vacancy concentration …

[HTML][HTML] Self-diffusion in garnet-type Li7La3Zr2O12 solid electrolytes

N Kuganathan, MJD Rushton, RW Grimes, JA Kilner… - Scientific Reports, 2021 - nature.com
Abstract Tetragonal garnet-type Li 7 La3Zr2O12 is an important candidate solid electrolyte
for all-solid-state lithium ion batteries because of its high ionic conductivity and large …

Elucidating the Importance of Quaternary Dopants in Stabilizing Cubic LLZO at Low Temperature

S Umesh, VK Jayaraman… - The Journal of Physical …, 2024 - ACS Publications
Future-generation solid-state Li batteries could benefit from the use of garnet-type
Li7La3Zr2O12 (LLZO) as an electrolyte. However, attaining a stable and highly ionic …