Engineering luminescent metal nanoclusters for sensing applications

S Qian, Z Wang, Z Zuo, X Wang, Q Wang… - Coordination Chemistry …, 2022 - Elsevier
Metal nanoclusters (MNCs) have ultrasmall size (≤ 3 nm), precise molecular structure,
strong luminescence, size-sensitive physicochemical properties, engineerable metallic …

[HTML][HTML] Emerging ultrasmall luminescent nanoprobes for in vivo bioimaging

S Li, J Wei, Q Yao, X Song, J Xie, H Yang - Chemical Society Reviews, 2023 - pubs.rsc.org
Photoluminescence (PL) imaging has become a fundamental tool in disease diagnosis,
therapeutic evaluation, and surgical navigation applications. However, it remains a big …

Interactions of metal nanoclusters with light: fundamentals and applications

T Chen, H Lin, Y Cao, Q Yao, J Xie - Advanced Materials, 2022 - Wiley Online Library
The interactions of materials with light determine their applications in various fields. In the
past decade, ultrasmall metal nanoclusters (NCs) have emerged as a promising class of …

Elucidating the Near-Infrared Photoluminescence Mechanism of Homometal and Doped M25(SR)18 Nanoclusters

Z Liu, M Zhou, L Luo, Y Wang, E Kahng… - Journal of the American …, 2023 - ACS Publications
More than a decade of research on the photoluminescence (PL) of classic Au25 (SR) 18 and
its doped nanoclusters (NCs) still leaves many fundamental questions unanswered due to …

Thiolate‐protected metal nanoclusters: recent development in synthesis, understanding of reaction, and application in energy and environmental field

T Kawawaki, A Ebina, Y Hosokawa, S Ozaki, D Suzuki… - Small, 2021 - Wiley Online Library
Metal nanoclusters (NCs), which are composed of about 250 or fewer metal atoms, possess
great potential as novel functional materials. Fundamental research on metal NCs gradually …

Active-Site Tailoring of Gold Cluster Catalysts for Electrochemical CO2 Reduction

Y Sun, X Liu, K Xiao, Y Zhu, M Chen - ACS Catalysis, 2021 - ACS Publications
Constructing the structure and composition of active sites of catalysts to discriminate
between reaction molecules remains a grand challenge in heterogeneous catalysis, as the …

Symmetry breaking of atomically precise fullerene-like metal nanoclusters

JH Huang, Y Si, XY Dong, ZY Wang… - Journal of the …, 2021 - ACS Publications
Here we report a neutral fullerene-like core–shell homosilver Ag13@ Ag20 nanocluster that
is fully protected by an achiral bidentate thiolate ligand (9, 12-dimercapto-1, 2-closo …

Identifying the real chemistry of the synthesis and reversible transformation of AuCd bimetallic clusters

H Xiang, H Yan, J Liu, R Cheng, CQ Xu… - Journal of the …, 2022 - ACS Publications
The capability of precisely constructing bimetallic clusters with atomic accuracy provides
exciting opportunities for establishing their structure–property correlations. However, the …

[HTML][HTML] Toward the creation of high-performance heterogeneous catalysts by controlled ligand desorption from atomically precise metal nanoclusters

T Kawawaki, Y Kataoka, M Hirata, Y Iwamatsu… - Nanoscale …, 2021 - pubs.rsc.org
Ligand-protected metal nanoclusters controlled by atomic accuracy (ie atomically precise
metal NCs) have recently attracted considerable attention as active sites in heterogeneous …

The factors dictating properties of atomically precise metal nanocluster electrocatalysts

H Yan, H Xiang, J Liu, R Cheng, Y Ye, Y Han, C Yao - Small, 2022 - Wiley Online Library
Metal nanoparticles occupy an important position in electrocatalysis. Unfortunately, by using
conventional synthetic methodology, it is a great challenge to realize the monodisperse …