[HTML][HTML] Recent Advances of Magnetite (Fe3O4)-Based Magnetic Materials in Catalytic Applications

M Liu, Y Ye, J Ye, T Gao, D Wang, G Chen, Z Song - Magnetochemistry, 2023 - mdpi.com
Catalysts play a critical role in producing most industrial chemicals and are essential to
environmental remediation. Under the demands of sustainable development, environment …

[HTML][HTML] Vapor-phase decomposition of dimethyl methylphosphonate (DMMP), a sarin surrogate, in presence of metal oxides

S Mukhopadhyay, M Schoenitz, EL Dreizin - Defence Technology, 2021 - Elsevier
Chemical warfare agents (CWA) are stockpiled in large quantities across the globe. Agents
stored in inaccessible facilities need to be destroyed rapidly without dispersing the …

High-temperature decomposition of diisopropyl methylphosphonate on alumina: mechanistic predictions from ab initio molecular dynamics

S Biswas, BM Wong - The Journal of Physical Chemistry C, 2021 - ACS Publications
The enhanced degradation of organophosphorous-based chemical warfare agents (CWAs)
on metal oxide surfaces holds immense promise for neutralization efforts; however, the …

Understanding Dimethyl Methylphosphonate Adsorption and Decomposition on Mesoporous CeO2

T Li, R Tsyshevsky, L Algrim, M McEntee… - … Applied Materials & …, 2021 - ACS Publications
The increased risk of chemical warfare agent usage around the world has intensified the
search for high-surface-area materials that can strongly adsorb and actively decompose …

Decomposition of the Toxic Nerve Agent Sarin on Oxygen Vacancy Sites of Rutile TiO2(110)

C Tesvara, CJ Karwacki, P Sautet - The Journal of Physical …, 2023 - ACS Publications
To design effective personal protective equipment against chemical attacks, the
understanding of chemical warfare agents (CWAs) decomposition chemistry is crucial. Metal …

Adsorption and decomposition of dimethyl methylphosphonate on size-selected zirconium oxide trimer clusters

MA Denchy, L Wang, N Blando, L Hansen… - The Journal of …, 2021 - ACS Publications
In recent years, zirconium hydroxide powder and zirconium-based metal organic
frameworks have found promising applications as chemical warfare agent (CWA) …

Oxidative decomposition of dimethyl methylphosphonate on rutile TiO 2 (110): the role of oxygen vacancies

C Tesvara, C Walenta, P Sautet - Physical Chemistry Chemical Physics, 2022 - pubs.rsc.org
The decomposition of dimethyl methylphosphonate (DMMP,(CH3O) 2P (O)(CH3)), a
simulant to the toxic nerve agent Sarin, on the rutile TiO2 (110) surface has been studied …

Highly vertical 3D bio-inspired hierarchical and multiscale superstructures on microcantilever for gas sensing of organophosphorous agents

G Thomas, V Keller, D Spitzer - Applied Materials Today, 2022 - Elsevier
Microgravimetric sensors offer promising solution to detect volatile compounds. However,
they suffer from a low surface-to-volume ratio limiting the maximum amount of adsorbate that …

Titania nanomaterials for sarin decomposition: understanding fundamentals

T Li, R Tsyshevsky, M McEntee, EM Durke… - ACS Applied Nano …, 2022 - ACS Publications
While TiO2-based materials have been attracting growing interest in combating chemical
warfare agents (CWAs), their usefulness and details of chemical mechanisms remain …

Kinetics and adsorption calculations: Insights into the MgO-catalyzed detoxification of simulants of organophosphorus biocides

GI Almerindo, SC Buratto, EH Wanderlind… - Journal of Materials …, 2020 - pubs.rsc.org
We report the targeted decomposition of the organophosphate methyl paraoxon by means of
its transesterification with 1-propanol catalyzed by magnesium oxide. Catalyst …