The chiral oxazoline motif is present in many ligands that have been extensively applied in a
series of important metal-catalyzed enantioselective reactions. This Review aims to provide …

The chemistry related to the exploration of cyclic N-sulfonyl ketimines and their derivatives
has attracted significant attention in the last few decades because of their intriguing …

Bidentate P, N ligands, integrating phosphine and nitrogen donors, are highlighted for their
versatile characteristics, offering both electronic and steric tunability. Their hemilabile nature …

Nickel catalysts of chiral pyrox ligands promoted enantioselective reductive arylation and
heteroarylation of aldimines, using directly (hetero) aryl halides and sulfonates. The catalytic …

We report broadly applicable copper catalytic conditions for the diastereoselective and
enantioselective 1, 2-addition of 1, 1-diborylalkanes to cyclic ketimines and α-imino esters …

Highly enantioselective rhodium‐catalyzed addition of arylboroxines to N‐unprotected
ketimines is realized for the first time by employing chiral BIBOP‐type ligands with a Rh …

Chiral gem (1, 1)-diaryl containing tertiary or quaternary stereogenic centers are present in
many natural products and important pharmacophores. While numerous catalytic …

The chemistry of cyclic imines has been gaining importance in the last decade because of
their broad spectrum of applications and biological importance. This review focuses on the …

We firstly describe a silver-catalyzed direct C–H functionalization of cyclic aldimines with
cyclopropanols and cyclobutanols via a radical-mediated C–C bond cleavage strategy. The …

A new type of ferrocene-based phosphine-oxazoline ligand has been prepared over a few
simple steps. An iridium complex of this ligand is air stable and exhibits excellent …