The Current Understanding of Mechanistic Pathways in Zeolite Crystallization

AJ Mallette, K Shilpa, JD Rimer - Chemical Reviews, 2024 - ACS Publications
Zeolite catalysts and adsorbents have been an integral part of many commercial processes
and are projected to play a significant role in emerging technologies to address the …

Dynamic imaging of interfacial electrochemistry on single Ag nanowires by azimuth-modulated plasmonic scattering interferometry

G Wu, C Qian, WL Lv, X Zhao, XW Liu - Nature Communications, 2023 - nature.com
Direct visualization of surface chemical dynamics in solution is essential for understanding
the mechanisms involved in nanocatalysis and electrochemistry; however, it is challenging …

Discovering relationships between OSDAs and zeolites through data mining and generative neural networks

Z Jensen, S Kwon, D Schwalbe-Koda, C Paris… - ACS central …, 2021 - ACS Publications
Organic structure directing agents (OSDAs) play a crucial role in the synthesis of micro-and
mesoporous materials especially in the case of zeolites. Despite the wide use of OSDAs …

Silanol-engineered nonclassical growth of zeolite nanosheets from oriented attachment of amorphous protozeolite nanoparticles

Q Zhang, J Li, X Wang, G He, L Li, J Xu… - Journal of the …, 2023 - ACS Publications
Zeolite nonclassical growth via particle attachment has been proposed for two decades, yet
the attachment mechanism and kinetic regulation remain elusive. Here, nonclassical growth …

A survey on zeolite synthesis and the crystallization process: Mechanism of nucleation and growth steps

Z Asgar Pour, YA Alassmy, KO Sebakhy - Crystals, 2023 - mdpi.com
Zeolites, as a class of crystalline minerals, find a wide range of applications in various fields,
such as catalysis, separation, and adsorption. More recently, these materials have also been …

Synthesis of NaA zeolite via the mesoscale reorganization of submolten salt depolymerized kaolin: A mechanistic study

X Chen, Y Wang, C Wang, J Xu, T Li, Y Yue, X Bi… - Chemical Engineering …, 2023 - Elsevier
Deep understanding of the formation mechanism is crucial to the rational design and
controllable synthesis of zeolites with desired pore architecture and acidity. Herein, we take …

Structural and electronic switching of a single crystal 2D metal-organic framework prepared by chemical vapor deposition

FJ Claire, MA Solomos, J Kim, G Wang… - Nature …, 2020 - nature.com
The incorporation of metal-organic frameworks into advanced devices remains a desirable
goal, but progress is hindered by difficulties in preparing large crystalline metal-organic …

Spontaneous pillaring of pentasil zeolites

R Jain, A Chawla, N Linares… - Advanced …, 2021 - Wiley Online Library
Conventional methods to prepare hierarchical zeolites depend upon the use of organic
structure‐directing agents and often require multiple synthesis steps with limited product …

Synthesis–structure–activity relations in Fe-CHA for C–H activation: control of Al distribution by interzeolite conversion

J Devos, ML Bols, D Plessers, CV Goethem… - Chemistry of …, 2019 - ACS Publications
The search for structurally relevant Al arrangements in zeolites is an important endeavor for
single-site catalysis. Little is known about the mechanisms and zeolite dynamics during …

In situ imaging of two-dimensional surface growth reveals the prevalence and role of defects in zeolite crystallization

MK Choudhary, R Jain… - Proceedings of the …, 2020 - National Acad Sciences
Zeolite crystallization predominantly occurs by nonclassical pathways involving the
attachment of complex (alumino) silicate precursors to crystal surfaces, yet recurrent images …