Energy-related small molecule activation reactions: oxygen reduction and hydrogen and oxygen evolution reactions catalyzed by porphyrin-and corrole-based …

W Zhang, W Lai, R Cao - Chemical reviews, 2017 - ACS Publications
Globally increasing energy demands and environmental concerns related to the use of fossil
fuels have stimulated extensive research to identify new energy systems and economies that …

Bioinspired N4-metallomacrocycles for electrocatalytic oxygen reduction reaction

Y Li, N Wang, H Lei, X Li, H Zheng, H Wang… - Coordination Chemistry …, 2021 - Elsevier
Oxygen reduction reaction (ORR) is an important process involved in natural and artificial
energy conversion schemes. As inspired by cytochrome c oxidases (CcOs), which are …

Controlling Oxygen Reduction Selectivity through Steric Effects: Electrocatalytic Two‐Electron and Four‐Electron Oxygen Reduction with Cobalt Porphyrin …

B Lv, X Li, K Guo, J Ma, Y Wang, H Lei… - Angewandte Chemie …, 2021 - Wiley Online Library
Achieving a selective 2 e− or 4 e− oxygen reduction reaction (ORR) is critical but
challenging. Herein, we report controlling ORR selectivity of Co porphyrins by tuning only …

Highly Efficient and Selective Photocatalytic CO2 Reduction to CO in Water by a Cobalt Porphyrin Molecular Catalyst

A Call, M Cibian, K Yamamoto, T Nakazono… - Acs …, 2019 - ACS Publications
The performance of a water-soluble cobalt porphyrin ([{meso-tetra (4-sulfonatophenyl)
porphyrinato} cobalt (III)], CoTPPS) as a catalyst for the photoreduction of CO2 in fully …

Photochemical CO2 Reduction Driven by Water-Soluble Copper(I) Photosensitizer with the Catalysis Accelerated by Multi-Electron Chargeable Cobalt Porphyrin

X Zhang, M Cibian, A Call, K Yamauchi, K Sakai - ACS Catalysis, 2019 - ACS Publications
Without using precious elements, a highly efficient and selective molecular-based
photocatalytic system for CO2-to-CO conversion in fully aqueous media has been …

Carbon nanotube-templated synthesis of covalent porphyrin network for oxygen reduction reaction

I Hijazi, T Bourgeteau, R Cornut… - Journal of the …, 2014 - ACS Publications
The development of innovative techniques for the functionalization of carbon nanotubes that
preserve their exceptional quality, while robustly enriching their properties, is a central issue …

Cobalt porphyrins as homogeneous catalysts for water oxidation

T Nakazono, AR Parent, K Sakai - Chemical Communications, 2013 - pubs.rsc.org
Three water-soluble cobalt porphyrins have been investigated as water oxidation catalysts
via photo-initiation using RuII (bpy) 32+/Na2S2O8. The pH dependence of the turnover …

Recent progress on metalloporphyrin-based hydrogen evolution catalysis

BB Beyene, CH Hung - Coordination Chemistry Reviews, 2020 - Elsevier
Designing an energy-efficient and cost-effective system for hydrogen (H 2) generation from
water or proton source remains as a challenge. Precious and rare earth metals such as …

Gold nanofilms at liquid–liquid interfaces: an emerging platform for redox electrocatalysis, nanoplasmonic sensors, and electrovariable optics

MD Scanlon, E Smirnov, TJ Stockmann… - Chemical reviews, 2018 - ACS Publications
The functionality of liquid–liquid interfaces formed between two immiscible electrolyte
solutions (ITIES) can be markedly enhanced by modification with supramolecular …

Attaching cobalt corroles onto carbon nanotubes: verification of four-electron oxygen reduction by mononuclear cobalt complexes with significantly improved efficiency

J Meng, H Lei, X Li, J Qi, W Zhang, R Cao - ACS Catalysis, 2019 - ACS Publications
Cobalt complexes have been extensively explored in catalyzing the oxygen reduction
reaction (ORR), which is the cathode reaction in fuel cells. Although they show high …