Structural flexibility in metal-organic cages

AE Martín Díaz, JEM Lewis - Frontiers in Chemistry, 2021 - frontiersin.org
Metal-organic cages (MOCs) have emerged as a diverse class of molecular hosts with
potential utility across a vast spectrum of applications. With advances in single-crystal X-ray …

Better Together: Functional Heterobimetallic Macrocyclic and Cage‐like Assemblies

M Hardy, A Lützen - Chemistry–A European Journal, 2020 - Wiley Online Library
Metallosupramolecular chemistry has attracted the interest of generations of researches due
to the versatile properties and functionalities of oligonuclear coordination complexes. Quite …

Redox active [Pd 2 L 4] 4+ cages constructed from rotationally flexible 1, 1′-disubstituted ferrocene ligands

RAS Vasdev, JA Findlay, AL Garden… - Chemical …, 2019 - pubs.rsc.org
Two new ferrocene-containing [Pd2 (LFc) 4] 4+(X−) 4 (where X−= BF4− or SbF6−) self-
assembled cages (C· BF4 and C· SbF6) were synthesised from the known, rotationally …

Fast, solvent-free synthesis of ferrocene-containing organic cages via dynamic covalent chemistry in the solid state

T Kunde, T Pausch, PA Guńka, M Krzyżanowski… - Chemical …, 2022 - pubs.rsc.org
A simple, solvent-free synthetic protocol towards the synthesis of organic self-assembled
macromolecules has been established. By employing mechanochemistry using glassware …

New ferrocene–triazole derivatives for multisignaling detection of Cu2+ in aqueous medium and their antibacterial activity

J Xu, Y Yang, H Baigude, H Zhao - … Acta Part A: Molecular and Biomolecular …, 2020 - Elsevier
Ferrocene–based naphthalene or quinoline receptors 1–4 linked by triazole were designed
and synthesized. Their recognition properties of metal cations have been investigated …

Ferrocene-Derived Palladium (II)-Based Metallosupramolecular Structures: Synthesis, Guest Interaction, and Stimulus-Responsiveness Studies

WDJ Tremlett, T Söhnel, JD Crowley… - Inorganic …, 2023 - ACS Publications
Using ferrocene-based ligand systems, a series of heterobimetallic architectures of the
general formula [Pd m L n] x+ were designed with the aim of installing an opening and …

Synthesis of an alternating copolymer of the dense 1,2,3‐triazole backbone carrying t‐butyl ester and nitrile side chains

L Xu, M Nakahata, Y Kamon… - Journal of Polymer …, 2024 - Wiley Online Library
In these decades, synthesis of polymers with controlled monomer sequences has been of
increasing importance in polymer chemistry. When we tested synthesis of a heterodimer of 4 …

Self‐Assembly of a Redox Active, Metallosupramolecular [Pd3L6]6+ Complex Using a Rotationally Flexible Ferrocene Ligand

RAS Vasdev, JA Findlay, DR Turner… - Chemistry–An Asian …, 2021 - Wiley Online Library
A new ferrocene‐containing [Pd3 (L4EFc) 6] 6+(X−) 6 (C⋅ BF4 and C⋅ SbF6 where X=
BF4− or SbF6−) self‐assembled double‐walled triangle has been synthesized from the …

Ferrocene: an exotic building block for supramolecular assemblies

C Guchhait, V Suriyaa, N Sahu, SD Sarkar… - Chemical …, 2023 - pubs.rsc.org
Ferrocene (Fc), a classical organometallic complex, has found potential applications in
ligand design, catalysis, and analytical, biological, medicinal and materials chemistry. In …

Using Complementary Ligand Denticity to Direct Metallosupramolecular Structure about Metal Ions with Square‐Planar Geometry

D Preston, PE Kruger - ChemPlusChem, 2020 - Wiley Online Library
An understanding of methods to control the structure of self‐assembled architectures is
central to the efforts of chemists interested in self‐assembly synthesis. Metal ions with …