Combustion chemistry of aromatic hydrocarbons

H Jin, W Yuan, W Li, J Yang, Z Zhou, L Zhao… - Progress in Energy and …, 2023 - Elsevier
Aromatic hydrocarbons are important components of petroleum-based transportation fuels,
biomass, coal, and solid waste, etc. The reaction kinetics of aromatic hydrocarbons largely …

Experimental techniques to gain mechanistic insight into fast pyrolysis of lignocellulosic biomass: A state-of-the-art review

A Nanduri, SS Kulkarni, PL Mills - Renewable and Sustainable Energy …, 2021 - Elsevier
This review focuses on identifying recent advances in experimental techniques used to
probe gas-phase reactive/stable intermediates in fast pyrolysis (FP). Potential spectroscopic …

[HTML][HTML] CRF-PEPICO: Double velocity map imaging photoelectron photoion coincidence spectroscopy for reaction kinetics studies

B Sztáray, K Voronova, KG Torma, KJ Covert… - The Journal of …, 2017 - pubs.aip.org
Photoelectron photoion coincidence (PEPICO) spectroscopy could become a powerful tool
for the time-resolved study of multi-channel gas phase chemical reactions. Toward this goal …

Comprehensive Kinetics on the C7H7 Potential Energy Surface under Combustion Conditions

C Martí, HA Michelsen, HN Najm… - The Journal of Physical …, 2023 - ACS Publications
The automated kinetics workflow code, KinBot, was used to explore and characterize the
regions of the C7H7 potential energy surface that are relevant to combustion environments …

Continuous butadiyne addition to propargyl: A radical-efficient pathway for polycyclic aromatic hydrocarbons

H Jin, L Xing, J Yang, Z Zhou, F Qi… - The Journal of Physical …, 2021 - ACS Publications
Polycyclic aromatic hydrocarbons (PAHs) play a crucial role in soot inception, interstellar
evolution, and nanomaterial synthesis. Although several mechanisms, such as hydrogen …

Experimental Observation of Hydrocarbon Growth by Resonance‐Stabilized Radical–Radical Chain Reaction

DE Couch, AJ Zhang, CA Taatjes… - Angewandte …, 2021 - Wiley Online Library
Rapid molecular‐weight growth of hydrocarbons occurs in flames, in industrial synthesis,
and potentially in cold astrochemical environments. A variety of high‐and low‐temperature …

First aromatic ring formation by the radical-chain reaction of vinylacetylene and propargyl

H Jin, L Xing, D Liu, J Hao, J Yang, A Farooq - Combustion and Flame, 2021 - Elsevier
Recent investigations illustrated that clustering of hydrocarbons by radical-chain reaction
(CHRCR) mechanism provides key mechanistic steps for the rapid synthesis of polycyclic …

The Identity and Chemistry of C7H7 Radicals Observed during Soot Formation

JA Rundel, C Martí, J Zádor, PE Schrader… - The Journal of …, 2023 - ACS Publications
We used aerosol mass spectrometry coupled with tunable synchrotron photoionization to
measure radical and closed-shell species associated with particle formation in premixed …

C7 reaction mechanism and its self-imitation in the kinetic modeling of PAH formation

H Jin, A Farooq - Combustion and Flame, 2023 - Elsevier
Polycyclic aromatic hydrocarbons (PAHs), serving as critical soot precursors, are formed via
complicated chemical processes, such as the first aromatic ring formation and the aromatic …

Vacuum ultraviolet photoionization of complex chemical systems

O Kostko, B Bandyopadhyay… - Annual review of physical …, 2016 - annualreviews.org
Tunable vacuum ultraviolet (VUV) radiation coupled to mass spectrometry is applied to the
study of complex chemical systems. The identification of novel reactive intermediates and …