Structure–property correlation in oxide-ion and proton conductors for clean energy applications: recent experimental and computational advancements

M Coduri, M Karlsson, L Malavasi - Journal of Materials Chemistry A, 2022 - pubs.rsc.org
In the last decade, the field of oxide-ion and proton conductors continued to trigger a
significant amount of basic research aimed at improving the properties and the …

High oxide-ion conductivity through the interstitial oxygen site in Ba7Nb4MoO20-based hexagonal perovskite related oxides

M Yashima, T Tsujiguchi, Y Sakuda, Y Yasui… - Nature …, 2021 - nature.com
Oxide-ion conductors are important in various applications such as solid-oxide fuel cells.
Although zirconia-based materials are widely utilized, there remains a strong motivation to …

High oxide ion and proton conductivity in a disordered hexagonal perovskite

S Fop, KS McCombie, EJ Wildman, JMS Skakle… - Nature materials, 2020 - nature.com
Oxide ion and proton conductors, which exhibit high conductivity at intermediate
temperature, are necessary to improve the performance of ceramic fuel cells. The crystal …

B-Site Deficient Hexagonal Perovskites: Structural Stability, Ionic Order-Disorder and Electrical Properties

X Yang, AJ Fernández–Carrión, X Geng… - Progress in Solid State …, 2024 - Elsevier
This review presents an overview on the structures and electrical properties of B-site
deficient hexagonal perovskite oxides, which have been receiving increasing attention as …

High Proton Conductivity in Ba5Er2Al2ZrO13, a Hexagonal Perovskite-Related Oxide with Intrinsically Oxygen-Deficient Layers

T Murakami, JR Hester, M Yashima - Journal of the American …, 2020 - ACS Publications
For the development of proton-based electrolytes, high proton conductivity at intermediate
temperatures (300–600° C) is crucial, but the available materials have been confined to a …

High Oxide‐Ion Conductivity in a Hexagonal Perovskite‐Related Oxide Ba7Ta3.7Mo1.3O20.15 with Cation Site Preference and Interstitial Oxide Ions

T Murakami, T Shibata, Y Yasui, K Fujii, JR Hester… - Small, 2022 - Wiley Online Library
Solid oxide‐ion conductors are crucial for enabling clean and efficient energy devices such
as solid oxide fuel cells. Hexagonal perovskite‐related oxides have been placed at the …

Hexagonal perovskite derivatives: a new direction in the design of oxide ion conducting materials

S Fop, KS McCombie, EJ Wildman… - Chemical …, 2019 - pubs.rsc.org
Various structural families have been reported to support oxide ion conductivity; among
these, perovskite conductors have received particular attention. The perovskite structure is …

Hydration and ionic conduction mechanisms of hexagonal perovskite derivatives

S Fop, JA Dawson, AD Fortes, C Ritter… - Chemistry of …, 2021 - ACS Publications
High ionic conductivity has been recently reported in hexagonal perovskite derivative
materials. These systems constitute a promising class of novel electrolytes for application in …

Enhanced Oxygen Ion Conductivity and Mechanistic Understanding in Ba3Nb1–xVxMoO8.5

S Fop, K McCombie, RI Smith… - Chemistry of …, 2020 - ACS Publications
Significant oxide ion conductivity has recently been reported in the cation-deficient
hexagonal perovskite derivative Ba3NbMoO8. 5. This system exhibits considerable anion …

Proton and oxide ion conductivity in palmierite oxides

S Fop, JA Dawson, DN Tawse, MG Skellern… - Chemistry of …, 2022 - ACS Publications
Solid proton and oxide ion conductors have key applications in several hydrogen-based and
energy-related technologies. Here, we report on the discovery of significant proton and …