In this review, aspects of the syntheses, structures and magnetic properties of giant 3d and
3d/4f paramagnetic metal clusters in moderate oxidation states are discussed. The term …

In this review article, we discuss advances in the chemistry of metal carbonyl clusters
(MCCs) spanning the last three decades, with an emphasis on the more recent reports and …

The shape control of noble metal nanocrystals is crucial to their optical properties and
catalysis applications. In this Progress Report, the recent progress of shape‐controlled …

In the past, palladium as a member of the platinum group metals was mainly known as an
expensive noble metal. Probably, only fast hydrogen absorption into bulk palladium …

Precisely designing metal nanoparticles (NPs) is the cornerstone for maximizing their
efficiency in applications like catalysis or sensor technology. Metal–organic frameworks …

Although a few nanosized metal carbonyl clusters were already obtained in the seventies,
these structurally and compositionally well-defined molecules attracted the interest of …

The state of art of the chemical, spectroscopic and structural characterization of platinum
carbonyl clusters is reviewed. We begin by enlightening the fundamental contribution given …

Syntheses, properties and structures of nanosized palladium CO/PR3-ligated homo-and
heterometallic clusters containing up to 165 metal atoms are the focus of this review. The …

The molecular nanocluster [Ni36–x Pd5+ x (CO) 46] 6–(x= 0.41)(1 6–) was obtained from the
reaction of [NMe3 (CH2Ph)] 2 [Ni6 (CO) 12] with 0.8 molar equivalent of [Pd (CH3CN) …

Reactions of N, N′-di-n-butyl-2-amino-5-alcoholate-1, 4-benzoquinonemonoiminium L 1,
or N, N′-diisopropyl-2-amino-5-alcoholate-1, 4-benzoquinonemonoiminium L 2 with …