Biocatalytic reduction reactions from a chemist's perspective

F Hollmann, DJ Opperman… - Angewandte Chemie …, 2021 - Wiley Online Library
Reductions play a key role in organic synthesis, producing chiral products with new
functionalities. Enzymes can catalyse such reactions with exquisite stereo‐, regio‐and …

Transformation of biomass into commodity chemicals using enzymes or cells

AJJ Straathof - Chemical reviews, 2014 - ACS Publications
Biomass can be classified broadly as all the matter on the earth's surface of recent biological
origin. 1 Biomass includes plant materials such as trees, grasses, agricultural crops, algal …

Overcoming energetic barriers in acetogenic C1 conversion

A Katsyv, V Müller - Frontiers in Bioengineering and Biotechnology, 2020 - frontiersin.org
Currently one of the biggest challenges for society is to combat global warming. A solution to
this global threat is the implementation of a CO2-based bioeconomy and a H2-based …

Hydrogenation of carboxylic acids with a homogeneous cobalt catalyst

TJ Korstanje, J Ivar van der Vlugt, CJ Elsevier… - Science, 2015 - science.org
The reduction of esters and carboxylic acids to alcohols is a highly relevant conversion for
the pharmaceutical and fine-chemical industries and for biomass conversion. It is commonly …

Hydrocarbon synthesis via photoenzymatic decarboxylation of carboxylic acids

W Zhang, M Ma, MME Huijbers… - Journal of the …, 2019 - ACS Publications
A recently discovered photodecarboxylase from Chlorella variabilis NC64A (Cv FAP) bears
the promise for the efficient and selective synthesis of hydrocarbons from carboxylic acids …

Bioenergetic constraints for conversion of syngas to biofuels in acetogenic bacteria

J Bertsch, V Müller - Biotechnology for biofuels, 2015 - Springer
Synthesis gas (syngas) is a gas mixture consisting mainly of H 2, CO, and CO 2 and can be
derived from different sources, including renewable materials like lignocellulose. The …

[PDF][PDF] How Green is Biocatalysis? To Calculate is To Know.

Y Ni, D Holtmann, F Hollmann - ChemCatChem, 2014 - researchgate.net
Green chemistry aims to minimize the environmental hazards of chemical processes and
their products. Ever since its introduction by Anastas,[1] this principle has inspired …

Photobiocatalytic synthesis of chiral secondary fatty alcohols from renewable unsaturated fatty acids

W Zhang, JH Lee, SHH Younes, F Tonin… - Nature …, 2020 - nature.com
En route to a bio-based chemical industry, the conversion of fatty acids into building blocks
is of particular interest. Enzymatic routes, occurring under mild conditions and excelling by …

Characterization of carboxylic acid reductases as enzymes in the toolbox for synthetic chemistry

W Finnigan, A Thomas, H Cromar, B Gough… - …, 2017 - Wiley Online Library
Carboxylic acid reductase enzymes (CARs) meet the demand in synthetic chemistry for a
green and regiospecific route to aldehydes from their respective carboxylic acids. However …

Recent trends and novel concepts in cofactor-dependent biotransformations

S Kara, JH Schrittwieser, F Hollmann… - Applied microbiology …, 2014 - Springer
Cofactor-dependent enzymes catalyze a broad range of synthetically useful transformations.
However, the cofactor requirement also poses economic and practical challenges for the …