The use of transition metals to catalyse the addition of hydridoboranes to unsaturated
organic molecules was initially realised several decades ago. Although this area of …

The utility of carbazole in photo-, electro-, and medicinal applications has ensured its
widespread use also as the backbone in tridentate pincer ligands. In this review, the aim is …

A magnesium-catalyzed regiodivergent C–O bond cleavage protocol is presented. Readily
available magnesium catalysts achieve the selective hydroboration of a wide range of …

A cross-electrophile coupling reaction of epoxides and (hetero) aryl iodides that operates via
the merger of three catalytic cycles involving a Ni-, Ti-, and organic photoredox catalyst has …

The high catalytic reactivity of homoleptic tris (alkyl) lanthanum La {C (SiHMe2) 3} 3 is
highlighted by C− O bond cleavage in the hydroboration of esters and epoxides at room …

The reduction of unsaturated compounds is one of the most widely applied transformations
in organic synthesis. Aggressive reductants, highly pressurized hydrogen gas, and …

A ruthenium (II)-catalyzed highly selective Markovnikov hydrogenation of terminal epoxides
to secondary alcohols is reported. Diverse substitutions on the aryl ring of styrene oxides are …

Metal‐ligand cooperation has emerged as a versatile tool for substrate activation in
chemical reactivity. Herein, we provide the synthesis and characterization of a monoboranyl …

In this work, the molecular aluminium dihydride complex bearing an N, N'‐chelated
conjugated bis‐guanidinate (CBG) ligand is used as a catalyst for reducing a wide range of …

The development of the highly active pincer-type rhodium catalyst 2 for the nucleophilic
Meinwald rearrangement of functionalised terminal epoxides into methyl ketones under mild …