A review of the structural diversity of [P x S y] n− motifs and their potential application prospects in metal thiophosphates

Y Yang, M Song, X Wu, K Wu - Journal of Physics D: Applied …, 2021 - iopscience.iop.org
Metal thiophosphates have wide potential critical applications in various fields, such as
nonlinear optical materials, magnetic materials, photoluminescence materials and solid …

Molecular germanium selenophosphate salts: phase-change properties and strong second harmonic generation

CD Morris, I Chung, S Park, CM Harrison… - Journal of the …, 2012 - ACS Publications
A new series of germanium chalcophosphates with the formula A4GeP4Q12 (A= K, Rb, Cs;
Q= S, Se) have been synthesized. The selenium compounds are isostructural and crystallize …

Na 6 Mg 3 P 4 S 16 and RbMg 2 PS 4 Cl 2: two Mg-based thiophosphates with ultrawide bandgaps resulting from [MgS 6] and [MgS x Cl 6− x] octahedra

Y Huang, D Chu, X Hou, G Li, Y Zhang - Dalton Transactions, 2024 - pubs.rsc.org
Designing wide-bandgap chalcogenides is one of the most important ways of obtaining high-
performance infrared (IR) functional materials. In this work, two Mg-based metal …

Phase Transition and Second Harmonic Generation in Thiophosphates Ag2Cd(P2S6) and AgCd3(PS4)S2 Containing Two Second-Order Jahn–Teller Distorted …

YH Fan, XM Jiang, BW Liu, SF Li, WH Guo… - Inorganic …, 2017 - ACS Publications
Two new phases in the Ag–Cd–P–S system containing two second-order Jahn–Teller
(SOJT) distorted d10 cations (Cd2+ and Ag+), namely, Ag2Cd (P2S6)(1) and AgCd3 (PS4) …

From BPS 4 to AB 3 P 2 S 10 (A= Na, K): cations inducing dimension reduction and bandgap enlargement

Y Huang, D Chu, Y Yun, W Xie, G Li, Y Zhang - Dalton Transactions, 2023 - pubs.rsc.org
Regulating the crystal structure by cations is one of the most effective methods to adjust the
performances of optical materials and enrich the structural chemistry of solid-state inorganic …

1/[ZrPSe6]: A Soluble Photoluminescent Inorganic Polymer and Strong Second Harmonic Generation Response of Its Alkali Salts

S Banerjee, CD Malliakas, JI Jang… - Journal of the …, 2008 - ACS Publications
1/∞[ZrPSe6−]: A Soluble Photoluminescent Inorganic Polymer and Strong Second
Harmonic Generation Response of Its Alkali Salts | Journal of the American Chemical …

Room Temperature Light Emission from the Low-Dimensional Semiconductors AZrPS6 (A = K, Rb, Cs)

S Banerjee, JM Szarko, BD Yuhas… - Journal of the …, 2010 - ACS Publications
The new semiconducting thiophosphate compounds KZrPS6, RbZrPS6, and CsZrPS6
exhibit red light emission at room temperature. The materials have longer …

Structural diversity of rare earth and transition metal thiophosphates

Y Wu, W Bensch - CrystEngComm, 2010 - pubs.rsc.org
Technological interest in the design of solid state materials has stimulated recent research
into the development of mild molten polychalcophosphate salt fluxes for the synthesis of …

Thiophosphates Containing Ag+ and Lone-Pair Cations with Interchiral Double Helix Show Both Ionic Conductivity and Phase Transition

YH Fan, HY Zeng, XM Jiang, MJ Zhang… - Inorganic …, 2017 - ACS Publications
Quaternary metal thiophosphates containing second-order Jahn–Teller distorted d10 Ag+
and lone-pair cations, Ag3Bi (PS4) 2 (1), Ag7Sn (PS4) 3 (2), and Ag7Pb (PS4) 3 (3), were …

Contribution of Disulfide S22– Anions to the Crystal and Electronic Structures in Ternary Sulfides, Ba12In4S19, Ba4M2S8 (M = Ga, In)

JW Liu, P Wang, L Chen - Inorganic Chemistry, 2011 - ACS Publications
Three semiconducting ternary sulfides have been synthesized from the mixture of elements
with about 20% excess of sulfur (to establish oxidant rich conditions) by solid-state reactions …