Pyridine is a ubiquitous building block for the design of very diverse ligand platforms, many
of which have become indispensable for catalytic transformations. Nevertheless, the …

The field of Surface Organometallic Chemistry (SOMC) aims to blend the positive attributes
of homogeneous and heterogeneous catalysis. Significant insight into heterogeneous …

The review is a follow-up of a previous article (I. Haiduc, J. Coord. Chem.(2019). DOI:
10.1080/00958972.2019. 1641702), which introduced structures with five-membered …

In this Perspective, we outline recent examples of homogeneous transition-metal hydrogen
transfer catalysts for which functionality within the complex's outer coordination sphere …

The phosphine-borane i Pr2P (o-C6H4) BFxyl2 (Fxyl= 3, 5-(F3C) 2C6H3) 1-Fxyl was found
to promote the reductive elimination of ethane from [AuMe2 (μ-Cl)] 2. Nuclear magnetic …

Designing and modulating the electronic and spatial environments surrounding metal
centers is a crucial issue in a wide range of chemistry fields that use organometallic …

Methods for in situ reversible control over ligand binding processes at transition metal
complexes can enable advances in switchable and tunable catalysis. After a brief overview …

The half-lantern PtII2 complexes [Pt (C∩ N)(μ-S∩ N)] 2 (C∩ N= 2-naphtylbenzothiazolate
1; 2-phenylbenzothiazolate 2; S∩ N= 2-thiopyridine) were crystallized with electron …

Bis (perchlorocatecholato) silane and bidentate N, N-or N, P-heteroleptic donors were
reacted to form hexacoordinated complexes. Depending on the ring strain and hemilability …

The thermochemistry of cation–macrocycle interactions in nickel pincer complexes bearing a
hemilabile aza-15-crown-5 or aza-18-crown-6 macrocycle is investigated and applied to …