[HTML][HTML] A comprehensive overview of directing groups applied in metal-catalysed C–H functionalisation chemistry

C Sambiagio, D Schönbauer, R Blieck… - Chemical Society …, 2018 - pubs.rsc.org
The present review is devoted to summarizing the recent advances (2015–2017) in the field
of metal-catalysed group-directed C–H functionalisation. In order to clearly showcase the …

CH Borylation: A Toolbox for Molecular Diversification

S Guria, MMM Hassan, B Chattopadhyay - Organic Chemistry …, 2024 - pubs.rsc.org
Iridium-catalyzed C–H activation and borylation has become as a powerful synthetic tool in
the past few decades because of the widespread applicability and versatility of organoboron …

Tuning the structure and electronic properties of B–N fused dipyridylanthracene and implications on the self-sensitized reactivity with singlet oxygen

K Liu, RA Lalancette, F Jäkle - Journal of the American Chemical …, 2019 - ACS Publications
We demonstrate that the modification of anthracene with B← N Lewis pairs at their periphery
serves as a highly effective tool to modify the electronic structure with important ramifications …

Synthesis and chiroptical properties of hexa‐, octa‐, and deca‐azaborahelicenes: influence of helicene size and of the number of boron atoms

C Shen, M Srebro‐Hooper, M Jean… - … A European Journal, 2017 - Wiley Online Library
Four members of a new class of cycloborylated hexa‐, octa‐, and deca‐helicenes (1 a–d)
have been prepared in enantiopure form, along with two cycloplatinated deca‐helicenes (1 …

Method for the Large-Scale Synthesis of Multifunctional 1,4-Dihydro-pyrrolo[3,2-b]pyrroles

M Tasior, O Vakuliuk, D Koga, B Koszarna… - The Journal of …, 2020 - ACS Publications
A thorough investigation has enabled the optimization of the synthesis of 1, 4-dihydro-
pyrrolo [3, 2-b] pyrroles. Although salts of such metals as vanadium, niobium, cerium, and …

Azabora [5] helicene charge‐transfer dyes show efficient and spectrally variable circularly polarized luminescence

Z Domínguez, R López‐Rodríguez… - … A European Journal, 2018 - Wiley Online Library
Three helicenes based on a borylated arylisoquinoline skeleton have been prepared in their
enantiopure forms and characterized with respect to their photophysical properties …

Benchmarking the performance of exchange-correlation functionals for predicting two-photon absorption strengths

MTP Beerepoot, MM Alam, J Bednarska… - Journal of Chemical …, 2018 - ACS Publications
The present work investigates the performance of exchange–correlation functionals in the
prediction of two-photon absorption (2PA) strengths. For this purpose, we considered six …

Locking the Coplanar Conformation of π‐Conjugated Molecules and Macromolecules Using Dynamic Noncovalent Bonds

C Zhu, L Fang - Macromolecular Rapid Communications, 2018 - Wiley Online Library
Torsional conformation of the backbone of a π‐conjugated molecule or macromolecule
shapes its solubility, optoelectronic characteristics, rheological behaviors, and ultimately …

Efficient thermally activated delayed fluorescence of functional phenylpyridinato boron complexes and high performance organic light-emitting diodes

YJ Shiu, YT Chen, WK Lee, CC Wu, TC Lin… - Journal of Materials …, 2017 - pubs.rsc.org
A new series of functional phenylpyridinato boron complexes possessing thermally activated
delayed fluorescence (TADF) has been strategically designed and synthesized. These …

A Three‐Component Assembly Promoted by Boronic Acids Delivers a Modular Fluorophore Platform (BASHY Dyes)

FMF Santos, JN Rosa, NR Candeias… - … A European Journal, 2016 - Wiley Online Library
The modular assembly of boronic acids with Schiff‐base ligands enabled the construction of
innovative fluorescent dyes [boronic acid salicylidenehydrazone (BASHY)] with suitable …