Molecular main group metal hydrides
This review serves to document advances in the synthesis, versatile bonding, and reactivity
of molecular main group metal hydrides within Groups 1, 2, and 12–16. Particular attention …
of molecular main group metal hydrides within Groups 1, 2, and 12–16. Particular attention …
Organic aluminum hydrides catalyze nitrile hydroboration
W Liu, Y Ding, D Jin, Q Shen, B Yan, X Ma, Z Yang - Green Chemistry, 2019 - pubs.rsc.org
Economical and eco-friendly aluminum hydrides were shown to be highly efficient catalysts
for the solvent-free hydroboration of various nitriles using pinacolborane. The catalytic …
for the solvent-free hydroboration of various nitriles using pinacolborane. The catalytic …
Aluminum-Hydride-Catalyzed Hydroboration of Carbon Dioxide
CC Chia, YC Teo, N Cham, SYF Ho, ZH Ng… - Inorganic …, 2021 - ACS Publications
This study describes the first use of a bis (phosphoranyl) methanido aluminum hydride,[ClC
(PPh2NMes) 2AlH2](2, Mes= Me3C6H2), for the catalytic hydroboration of CO2. Complex 2 …
(PPh2NMes) 2AlH2](2, Mes= Me3C6H2), for the catalytic hydroboration of CO2. Complex 2 …
Electronically Unsaturated Three‐Coordinate Aluminum Hydride and Organoaluminum Cations
B Prashanth, M Bhandari, S Ravi… - … A European Journal, 2018 - Wiley Online Library
New three‐coordinate and electronically unsaturated aluminum hydride [LAlH]+[HB (C6F5)
3]−(LH=[{(2, 6‐iPr2C6H3N) P (Ph2)} 2N] H) and aluminum methyl [LAlMe]+[MeB (C6F5) 3] …
3]−(LH=[{(2, 6‐iPr2C6H3N) P (Ph2)} 2N] H) and aluminum methyl [LAlMe]+[MeB (C6F5) 3] …
Ligand Influence on Carbonyl Hydroboration Catalysis by Alkali Metal Hydridotriphenylborates [(L)M][HBPh3] (M=Li, Na, K)
H Osseili, D Mukherjee, TP Spaniol… - Chemistry–A European …, 2017 - Wiley Online Library
Abstract Alkali metal hydridotriphenylborates [(L1) M][HBPh3](L1= Me6TREN; M= Li, Na, K)
chemoselectively catalyze the hydroboration of carbonyls and CO2, with lithium being the …
chemoselectively catalyze the hydroboration of carbonyls and CO2, with lithium being the …
Zinc hydridotriphenylborates supported by a neutral macrocyclic polyamine
D Mukherjee, AK Wiegand, TP Spaniol, J Okuda - Dalton Transactions, 2017 - pubs.rsc.org
The zinc hydridotriphenylborates [(L) Zn (TMDS)][HBPh3] and [(L) ZnX][HBPh3](L=
Me4TACD, Me4 [12] aneN4; TMDS= N (SiHMe2) 2; X= Cl, Br, I) were synthesized by BPh3 …
Me4TACD, Me4 [12] aneN4; TMDS= N (SiHMe2) 2; X= Cl, Br, I) were synthesized by BPh3 …
Synthesis of linear and star poly (ε-caprolactone) with controlled and high molecular weights via cyclic trimeric phosphazene base catalyzed ring-opening …
H Li, N Zhao, C Ren, S Liu, Z Li - Polymer Chemistry, 2017 - pubs.rsc.org
Poly (ε-caprolactones)(PCLs) with low catalyst loading and high molecular weights are
highly desired considering their practical applications. In this work, cyclic trimeric …
highly desired considering their practical applications. In this work, cyclic trimeric …
[HTML][HTML] Lewis Acid-Initiated Ring-Opening Reactions of Five-and Six-Membered Cyclic Ethers Based on the Oxonium Ylide Intermediates
D Jiang, J Xiao, Y Zhang, K Liu, J Li, J Liu - Organics, 2024 - mdpi.com
In light of the small ring strain of five/six-membered cyclic ethers, constructing complex
molecules via ring-opening reactions has consistently been a highly challenging topic in …
molecules via ring-opening reactions has consistently been a highly challenging topic in …
Ruthenium-Catalyzed Selective Hydroboronolysis of Ethers
A ruthenium-catalyzed reaction of HBpin with substituted organic ethers leads to the
activation of C–O bonds, resulting in the formation of alkanes and boronate esters via hydro …
activation of C–O bonds, resulting in the formation of alkanes and boronate esters via hydro …
Deaggregation of Zinc Dihydride by Lewis Acids Including Carbon Dioxide in the Presence of Nitrogen Donors
F Ritter, LJ Morris, KN McCabe, TP Spaniol… - Inorganic …, 2021 - ACS Publications
Thermally sensitive polymeric zinc dihydride [ZnH2] n can conveniently be prepared by the
reaction of ZnEt2 with [AlH3 (NEt3)]. When reacted with CO2 (1 bar) in the presence of …
reaction of ZnEt2 with [AlH3 (NEt3)]. When reacted with CO2 (1 bar) in the presence of …