Highlighting the Rich Chemistry of the Allenone Moiety

JM Alonso, P Almendros - Advanced Synthesis & Catalysis, 2023 - Wiley Online Library
Conjugated and non‐conjugated allenones appear as recurring motifs in organic synthesis,
natural products and mechanistic investigations showing unique properties and …

Copper catalysts in the synthesis of five-membered N-polyheterocycles

N Kaur - Current Organic Synthesis, 2018 - ingentaconnect.com
Background: Due to significant biological activity associated with N-, O-and S-heterocycles,
a number of reports for their synthesis have appeared in recent decades. Traditional …

Gold-catalyzed oxidative rearrangement involving 1, 2-acyl migration: efficient synthesis of functionalized dihydro-γ-carbolines from α-(2-indolyl) propargylic alcohols …

L Wang, X Xie, Y Liu - Angewandte Chemie International …, 2013 - search.ebscohost.com
Smooth moves with a nifty side step: A gold‐catalyzed transformation of α‐(2‐indolyl)
propargylic alcohols with imines in the presence of the oxidant 8‐isopropylquinoline N …

Methods for metal and non-metal catalyzed synthesis of six-membered oxygen containing poly-heterocycles

N Kaur - Current Organic Synthesis, 2017 - ingentaconnect.com
In recent decades, a large number of reports related to synthesis of N, O and S containing
heterocycles have appeared owing to a wide variety of their biological activity. We need a …

Mercury-catalyzed synthesis of heterocycles

N Kaur - Synthetic Communications, 2018 - Taylor & Francis
Due to significant biological activity associated with N-, O-and S-heterocycles, a number of
reports for their synthesis have appeared in recent decades. Traditional approaches require …

Nickel (II)‐Catalyzed Asymmetric Propargyl and Allyl Claisen Rearrangements to Allenyl‐and Allyl‐Substituted β‐Ketoesters

Y Liu, H Hu, H Zheng, Y Xia, X Liu… - Angewandte Chemie …, 2014 - Wiley Online Library
Highly efficient catalytic asymmetric Claisen rearrangements of O‐propargyl β‐ketoesters
and O‐allyl β‐ketoesters have been accomplished under mild reaction conditions. In the …

Cascade Claisen rearrangement: rapid synthesis of polysubstituted salicylaldehydes and total syntheses of hemigossypol and gossypol

T Cao, Y Kong, K Luo, L Chen, S Zhu - Angewandte Chemie, 2018 - Wiley Online Library
A cascade Claisen rearrangement of a well‐organized maltol propargyl ether for the
construction of polysubstituted salicylaldehydes is reported. This reaction features high atom …

Leveraging Nonstrained C–C Bonds for Selective Carboacylation of an Unactivated Alkyne via Transient Dearomatization

J He, T Cao, K Chen, S Zhu - Organic Letters, 2024 - ACS Publications
Carboacylation of an unsaturated bond represents a powerful transformation. However, only
a few examples of carboacylation of alkyne have been reported through C–C bond scission …

Synthesis of Pyrrolidines and Pyrrolizidines with α‐Pseudoquaternary Centers by Copper‐Catalyzed Condensation of α‐Diazodicarbonyl Compounds and Aryl γ …

S Goudedranche, C Besnard, L Egger… - Angewandte Chemie …, 2016 - Wiley Online Library
N‐aryl γ‐lactams react intermolecularly with acceptor–acceptor diazo reagents, usually
dicarbonyl compounds, in a copper‐catalyzed process to yield functionalized pyrrolidines …

Synthesis of Mono-and Polyazole Hybrids Based on Polyfluoroflavones

MA Panova, KV Shcherbakov, EF Zhilina, YV Burgart… - Molecules, 2023 - mdpi.com
The possibility of functionalization of 2-(polyfluorophenyl)-4 H-chromen-4-ones, with them
having different numbers of fluorine atoms, with 1, 2, 4-triazole or imidazole under conditions …