Advances in (spectroscopic) characterization of the unusual electronic structures of open-
shell cobalt complexes bearing redox-active ligands, combined with detailed mapping of …

Valence tautomerism has had a remarkable impact on several branches of transition metal
chemistry. By switching between different valence tautomeric states, physicochemical …

The chemical vapor deposition of refractory metal nitrides requires volatile precursors and
has previously been achieved by using metal complexes containing a variety of imide …

The reactions of oxide [(dpp-bian) Al (μ2-O) 2Al (dpp-bian)](1)(dpp-bian= 1, 2-bis [(2, 6-
diisopropylphenyl) imino] acenaphthene) with phenyl-or cyclohexylisocyanates result in the …

Reactions of di‐tert‐butyldiphosphatetrahedrane (1) with cycloocta‐1, 5‐diene‐or
anthracene‐stabilised metalate anions of iron and cobalt consistently afford complexes of …

The reactivity of [(dpp-Bian) Al (H) 2Li (THF) 3](1)(dpp-Bian= 1, 2-bis [(2, 6-
diisopropylphenyl) imino] acenaphthene) and [(ArBIG-Bian) Al (H) 2Li (THF) 4](2)(ArBIG …

A series of the chlorido and alkoxychlorido titanium complexes of the general formula (dpp-
Bian) Ti (O i Pr) n Cl3–n, where dpp-Bian= 1, 2-bis [(2, 6-i Pr2C6H3) imino] acenaphthene …

Exploration of the local chemical space of molecular scaffolds by post-functionalization (PF)
is a promising route to discover novel molecules with desired structure and function. PF with …

The control of the redox reactivity, magnetic and optical properties of the different redox
states of complexes with redox‐active ligands permits their rational use in catalysis and …

Dehydrogenation of ammonia borane to well-defined products is an important but
challenging reaction. A dinuclear ruthenium complex with a Ru–Ru bond bearing a …