Recognition in the domain of molecular chirality: from noncovalent interactions to separation of enantiomers

P Peluso, B Chankvetadze - Chemical Reviews, 2022 - ACS Publications
It is not a coincidence that both chirality and noncovalent interactions are ubiquitous in
nature and synthetic molecular systems. Noncovalent interactivity between chiral molecules …

Noncovalent interactions in proteins and nucleic acids: Beyond hydrogen bonding and π-stacking

S Jena, J Dutta, KD Tulsiyan, AK Sahu… - Chemical Society …, 2022 - pubs.rsc.org
Understanding the noncovalent interactions (NCIs) among the residues of proteins and
nucleic acids, and between drugs and proteins/nucleic acids, etc., has extraordinary …

[HTML][HTML] Chalcogen bonding in coordination chemistry

KT Mahmudov, AV Gurbanov, VA Aliyeva… - Coordination Chemistry …, 2022 - Elsevier
The chalcogen bond (ChB) is defined as a noncovalent interaction between the electron
density deficient region (so-called as σ or π hole) of a covalently bonded chalcogen atom …

[PDF][PDF] Halogen bonds, chalcogen bonds, pnictogen bonds, tetrel bonds and other σ-hole interactions: A snapshot of current progress

L Brammer, A Peuronen… - … Section C: Structural …, 2023 - journals.iucr.org
We report here on the status of research on halogen bonds and other σ-hole interactions
involving p-block elements in Lewis acidic roles, such as chalcogen bonds, pnictogen bonds …

Molecular electrostatic potential and noncovalent interactions in derivatives of group 8 elements

A Daolio, A Pizzi, M Calabrese, G Terraneo… - Angewandte …, 2021 - Wiley Online Library
This communication reports experimental and theoretical evidences of σ‐hole interactions in
adducts between nitrogen or oxygen nucleophiles and tetroxides of osmium or other group 8 …

Anion⋅⋅⋅ Anion Interactions Involving σ‐Holes of Perrhenate, Pertechnetate and Permanganate Anions

A Daolio, A Pizzi, G Terraneo, A Frontera… - …, 2021 - Wiley Online Library
In this communication experimental and theoretical results are reported affording strong
evidence that interactions between electron rich atoms and the metal of tetroxide anions of …

Crystal engineering strategies towards halogen-bonded metal–organic multi-component solids: Salts, cocrystals and salt cocrystals

V Nemec, K Lisac, N Bedeković, L Fotović… - …, 2021 - pubs.rsc.org
Over the past several decades, halogen bonding has become a standard 'tool'in
supramolecular chemistry and particularly in crystal engineering. Traditionally, the study of …

On the importance of σ–hole interactions in crystal structures

A Frontera, A Bauzá - Crystals, 2021 - mdpi.com
Elements from groups 14–18 and periods 3–6 commonly behave as Lewis acids, which are
involved in directional noncovalent interactions (NCI) with electron-rich species (lone pair …

Molecular electrostatic potential topology analysis of noncovalent interactions

CH Suresh, S Anila - Accounts of Chemical Research, 2023 - ACS Publications
Conspectus The topology of molecular electrostatic potential (MESP), V (r), derived from a
reliable quantum chemical method has been used as a powerful tool for the study of …

On the importance of pnictogen and chalcogen bonding interactions in supramolecular catalysis

A Frontera, A Bauza - International Journal of Molecular Sciences, 2021 - mdpi.com
In this review, several examples of the application of pnictogen (Pn)(group 15) and
chalcogen (Ch) bonding (group 16) interactions in organocatalytic processes are gathered …