Rhenium (VII) oxo and imido complexes: synthesis, structures, and applications

CC Romão, FE Kühn, WA Herrmann - Chemical reviews, 1997 - ACS Publications
The first examples of organometallic derivatives of metal oxides appeared in a syncretic
fashion and were merely regarded as laboratory curiosities in a time where low oxidation …

Organorhenium dioxides as oxygen transfer systems: Synthesis, reactivity, and applications

RG Harms, WA Herrmann, FE Kuehn - Coordination Chemistry Reviews, 2015 - Elsevier
Organorhenium complexes are attracting interest because of their possible uses as
deoxygenation catalysts in the refinement of lignocellulosic biomass such as lignin …

Charge effects on oxygen atom transfer

SB Seymore, SN Brown - Inorganic Chemistry, 2000 - ACS Publications
The rhenium (V) complex [(HCpz3) ReOCl2]+([1]+), the tris (pyrazolyl) methane analogue of
the known tris (pyrazolyl) borate complex (HBpz3) ReOCl2 (2), has been prepared. The two …

Rhenium mixed-ligand complexes with S, N, S-tridentate thiosemicarbazone/thiosemicarbazide ligands

PIS Maia, HH Nguyen, A Hagenbach… - Dalton …, 2013 - pubs.rsc.org
Rhenium (V) complexes containing tridentate thiosemicarbazones/thiosemicarbazides
(H2L1) derived from N-[N′, N′-dialkylamino (thiocarbonyl)] benzimidoyl chlorides with 4, 4 …

Bipodal acylthiourea ligands as building blocks for bi-, tetra-, and polynuclear oxorhenium (V) complexes

HH Nguyen, PC Thang, A Rodenstein… - Inorganic …, 2011 - ACS Publications
Reactions of (NBu4)[ReOCl4] and 3, 3, 3′, 3′-tetraalkyl-1, 1′-isophthaloylbis (thioureas),
H2phth (R2tu) 2 where R= Et, i-Bu, in hot MeOH with the addition of Et3N give red products …

Rhenium and technetium complexes anchored by phosphines and scorpionates for radiopharmaceutical applications

I Santos, A Paulo, JDG Correia - Contrast Agents III …, 2005 - Springer
This review presents a comprehensive overview of the most significant developments in the
chemistry of technetium and rhenium complexes anchored by heterofunctionalized …

Efficient catalytic deoxygenation of epoxides using [tris (3, 5-dimethylpyrazolyl) hydridoborato] rhenium oxides

KP Gable, EC Brown - Organometallics, 2000 - ACS Publications
In situ reduction of Tp 'ReO3 (Tp '= tris (3, 5-dimethylpyrazolyl) hydridoborate) using
triphenylphosphine or triethyl phosphite allows generation of a reduced rhenium species …

A short ride on scorpionates: from d-to f-elements

A Paulo, JDG Correia, MPC Campello, I Santos - Polyhedron, 2004 - Elsevier
This paper presents an overview of progress involving group 7 elements and actinides with
scorpionate ligands. This includes oxides, polyhydrides and carbonyls of group 7 elements …

Synthesis of cationic rhenium (VII) oxo imido complexes and their tunability towards oxygen atom transfer

EA Ison, JE Cessarich, NE Travia… - Journal of the …, 2007 - ACS Publications
A facile method is described for the synthesis of cationic Re (VII) cis oxo imido complexes of
the form [Re (O)(NAr)(salpd)+](salpd= N, N '-propane-1, 3-diylbis (salicylideneimine)), 4,[Re …

Novel rhenium (V) oxo complexes containing bis (pyrazol-1-yl) acetate and bis (pyrazol-1-yl) sulfonate as tripodal N, N, O-heteroscorpionate ligands

M Porchia, G Papini, C Santini, GG Lobbia… - Inorganic …, 2005 - ACS Publications
Reactions of [NBu4][Re (O) Cl4] with bis (pyrazol-1-yl) methane (bpzm) and bis (pyrazol-1-
yl) acetate (Hbpza) and with the lithium salts lithium [bis (3, 5-dimethylpyrazol-1-yl) …