Cyanide-bridged assemblies with tricyanometalates
Prussian blue, Fe III 4 [Fe II (CN) 6] 3· nH 2 O (n= 14∼ 16), is one of the most classical mixed-
valence complexes and was used as pigments. Combinations of different metal ions lead to …
valence complexes and was used as pigments. Combinations of different metal ions lead to …
A turn-on luminescent europium probe for cyanide detection in water
SY Huang, VC Pierre - Chemical Communications, 2018 - pubs.rsc.org
A luminescent europium probe that responds to cyanide directly in water with a large nine-
fold turn-on of the EuIII centered time-gated luminescence is presented. Unlike other CN …
fold turn-on of the EuIII centered time-gated luminescence is presented. Unlike other CN …
Cyanido-Bridged Heterobimetallic Molecular Squares: Low-Dimensional Models of Prussian Blue Analogues and Beyond
MG Alexandru, D Visinescu, J Cano… - Crystal Growth & …, 2023 - ACS Publications
The cyanido-bridged square-like molecules with d/f metal ions occupying the corners of the
square are considered molecular models of the Prussian Blue Analogues (PBAs) because …
square are considered molecular models of the Prussian Blue Analogues (PBAs) because …
Anion-Induced Structural Diversity and Optical Chromism in a Series of Cyano-Bridged Heterometallic 3d-4f Coordination Polymers
The self-assembly reaction of the neutral dicyano-bis (1, 10-phenanthroline) iron (II)
complex with lanthanide ions (Ln= Eu (III), Gd (III), Er (III)) provided two different classes of …
complex with lanthanide ions (Ln= Eu (III), Gd (III), Er (III)) provided two different classes of …
Heterobimetallic cyanide-bridged Fe III (μ-CN) M II complexes (M= Mn and Cu): synthesis, structure and magnetism
S Ahmed, A Kumar, N Mukhopadhyay, F Lloret… - New Journal of …, 2022 - pubs.rsc.org
A controlled reaction in DMF/CH3CN between a facially disposed tricyanide-containing
building block (nBu4N)[FeIII (Tp)(CN) 3](Tp (–)= tris (pyrazol-1-yl) borate anion) and tailor …
building block (nBu4N)[FeIII (Tp)(CN) 3](Tp (–)= tris (pyrazol-1-yl) borate anion) and tailor …
Design of Fe III–Ln III binuclear complexes using compartmental ligands: synthesis, crystal structures, magnetic properties, and ab initio analysis
Three new binuclear FeIII–LnIII complexes, with similar structures, have been synthesized
using the end-off compartmental proligand, H2valpn, resulting from the Schiff condensation …
using the end-off compartmental proligand, H2valpn, resulting from the Schiff condensation …
The rational construction of diamond-like dysprosium–hexacyanometallate frameworks featuring dynamic magnetic behaviour
Four novel isostructural heterometallic dysprosium–hexacyanometallate frameworks,
namely {[Dy4 (L) 4 (H2O) 4 (CH3OH) 4M (CN) 6]· Cl· 8H2O} n and {[Dy4 (L) 4 (H2O) 4 …
namely {[Dy4 (L) 4 (H2O) 4 (CH3OH) 4M (CN) 6]· Cl· 8H2O} n and {[Dy4 (L) 4 (H2O) 4 …
A rare isostructural series of 3d–4f cyanido-bridged heterometallic squares obtained by assembling [Fe III {HB (pz) 3}(CN) 3]− and Ln III ions: synthesis, X-ray structure …
MG Alexandru, D Visinescu, B Cula, S Shova… - Dalton …, 2021 - pubs.rsc.org
A new series of cyanido-bridged {FeIIILnIII} 2 neutral molecular squares of general formula
[Fe {HB (pz) 3}(CN)(μ-CN) 2Ln (NO3) 2 (pyim)(Ph3PO)] 2· 2CH3CN [Ln= Ce (1), Pr (2), Nd …
[Fe {HB (pz) 3}(CN)(μ-CN) 2Ln (NO3) 2 (pyim)(Ph3PO)] 2· 2CH3CN [Ln= Ce (1), Pr (2), Nd …
Cyanido-bridged {Fe III Ln III} heterobimetallic chains assembled through the [Fe III {HB (pz) 3}(CN) 3]− complex as metalloligand: synthesis, crystal structure and …
A new series of cyanido-bridged {FeIIILnIII} heterobimetallic chains of general formula {[(NC)
FeIII {HB (pz) 3}(μ-CN) 2LnIII (bpdo)(NO3) 2 (H2O)]· CH3CN} n [HB (pz) 3−= hydrotris …
FeIII {HB (pz) 3}(μ-CN) 2LnIII (bpdo)(NO3) 2 (H2O)]· CH3CN} n [HB (pz) 3−= hydrotris …
Slow relaxation of the magnetization in a {CoIIIMnIII} heterometallic brick-wall network
The use of the cyanide-bearing dicobalt (III) complex (PPh 4) 2 [Co 2 III (μ− 2, 5-dpp)(CN) 8]
as a metalloligand towards [Mn (salen)(H 2 O)] ClO 4 afforded the heterobimetallic two …
as a metalloligand towards [Mn (salen)(H 2 O)] ClO 4 afforded the heterobimetallic two …