Bimetallic sites for catalysis: from binuclear metal sites to bimetallic nanoclusters and nanoparticles

L Liu, A Corma - Chemical Reviews, 2023 - ACS Publications
Heterogeneous bimetallic catalysts have broad applications in industrial processes, but
achieving a fundamental understanding on the nature of the active sites in bimetallic …

Electrocatalytic CO2 reduction to fuels: progress and opportunities

J Resasco, AT Bell - Trends in Chemistry, 2020 - cell.com
The electrochemical reduction of CO 2 remains an appealing option for storing renewable
energy in a chemical form. In this review, we assess progress in designing catalysts that …

Operando insights into nanoparticle transformations during catalysis

A Bergmann, B Roldan Cuenya - Acs Catalysis, 2019 - ACS Publications
Nanostructured materials play an important role in today's chemical industry, acting as
catalysts in heterogeneous thermal and electrocatalytic processes for chemical energy …

Operando surface studies on metal-oxide interfaces of bimetal and mixed catalysts

J Kim, H Choi, D Kim, JY Park - ACS Catalysis, 2021 - ACS Publications
The formation of metal-oxide interfaces in catalytic systems exhibits a synergistic
phenomenon between metal and reducible oxides, often referred to as the strong metal …

Maximizing the Catalytic Performance of Pd@AuxPd1−x Nanocubes in H2O2 Production by Reducing Shell Thickness to Increase Compositional Stability

Y Zhang, Z Lyu, Z Chen, S Zhu, Y Shi… - Angewandte …, 2021 - Wiley Online Library
We report a simple route based upon seed‐mediated growth to the synthesis of Pd@
AuxPd1− x (0.8≤ x≤ 1) core–shell nanocubes. Benefiting from the well‐defined {100} …

Moderate Surface Segregation Promotes Selective Ethanol Production in CO2 Hydrogenation Reaction over CoCu Catalysts

S Liu, C Yang, S Zha, D Sharapa, F Studt… - Angewandte …, 2022 - Wiley Online Library
Cobalt‐copper (CoCu) catalysts have industrial potential in CO/CO2 hydrogenation
reactions, and CoCu alloy has been elucidated as a major active phase during reactions …

Surface restructuring and predictive design of heterogeneous catalysts

F Tao, M Salmeron - Science, 2024 - science.org
Heterogeneous catalysts, which often consist of metal nanoparticles loaded on supports
such as metal oxides, can undergo several types of restructuring under reaction and …

Cobalt–Nickel Nanoparticles Supported on Reducible Oxides as Fischer–Tropsch Catalysts

C Hernández Mejía, JES van Der Hoeven… - ACS …, 2020 - ACS Publications
Efficient and more sustainable production of transportation fuels is key to fulfill the ever-
increasing global demand. In order to achieve this, progress in the development of highly …

(Ni, Cu)/hexagonal BN nanohybrids–New efficient catalysts for methanol steam reforming and carbon monoxide oxidation

AM Kovalskii, AT Matveev, ZI Popov, IN Volkov… - Chemical engineering …, 2020 - Elsevier
This work is aimed at the development of bimetallic (Ni 0.2 Cu 0.8) catalysts with hexagonal
boron nitride (h-BN) nanosheet (BNNS) supports and elucidating their catalytic activity in the …

Chemical Batteries with CO2

R Schlögl - Angewandte Chemie International Edition, 2022 - Wiley Online Library
Efforts to obtain raw materials from CO2 by catalytic reduction as a means of combating
greenhouse gas emissions are pushing the boundaries of the chemical industry. The …