Recent advances in the photocatalytic synthesis of aldehydes

Y Wang, XF Liu, WM He - Organic Chemistry Frontiers, 2023 - pubs.rsc.org
The synthesis of aldehyde compounds under mild conditions enabled by visible light-
induced organic reactions is highly attractive in modern chemistry. The reagents including …

Generation of New Synthons for Synthesis Through Activation of Nitromethane

W Wang, L Zhao, Y Zhang - ChemSusChem, 2024 - Wiley Online Library
Nitromethane is used a common solvent, stabilizer, and fuel additive. Nitromethane has also
been used as a sustainable building block and convenient reagent in chemical synthesis. In …

Site‐Selective Decarboxylative Direct Formylation of Nitrogen Heterocycles (Azaindoles, Indoles, Pyrroles) and Anilines Utilizing Glyoxylic Acid

JK Laha, MK Hunjan, T Maity… - Advanced Synthesis & …, 2023 - Wiley Online Library
A new method for formylation of nitrogen heterocycles overcoming the limitations of classical
approaches using a cheap feedstock formylating agent especially under mild and neutral …

Photoredox Catalyzed Thioformylation of Terminal Alkynes Using Nitromethane as a Formyl Source

MS Bhat, MA Ganie, MA Rizvi, S Raheem… - Organic …, 2022 - ACS Publications
A photoredox thioformylation of terminal alkynes using nitromethane as a formyl anion
equivalent, thereby leading to the synthesis of (E)-1, 2-difunctionalized acrylaldehyde, has …

Cation-π-interaction-facilitated, self-photocatalyzed and regioselective perfluoroalkylation of 3-aza-1, 5-dienes

R Yang, D Chen, S Lin, X Yang, X Hu, S Gao, L Shi… - Molecular …, 2023 - Elsevier
A self-photocatalyzed perfluoroalkylation/cyclization cascade of 3-aza-1, 5-dienes enabled
by an unprecedented cation-π-interaction is presented. The reaction proceeds with a great …

Catalytic Vilsmeier–Haack Reactions for C1-Deuterated Formylation of Indoles

J Xue, YS Zhang, Z Huan, JD Yang… - The Journal of Organic …, 2022 - ACS Publications
The Vilsmeier–Haack reaction is a powerful tool to introduce formyl groups into electron-rich
arenes, but its wide application is significantly restricted by stoichiometric employment of …

TBHP/Et3N-Promoted Chemoselective Formylation and Peroxidation of Pyrrolo[2,1-a]isoquinolines

X Huang, J Zhou, SC Pei, HL Cui - The Journal of Organic …, 2024 - ACS Publications
An efficient formylation of pyrrolo [2, 1-a] isoquinoline derivatives has been reached by the
use of TBHP (t BuOOH) and Et3N as the mediator. In this strategy, CHO and CDO can be …

Modulating confinement space in metal–organic frameworks enables highly selective indole C3-formylation

DY Zheng, T Zhang, R Bai, M Li, Y Gu - Chemical Communications, 2024 - pubs.rsc.org
Here, Selective C3-formylation of indole was achieved under mild conditions using a metal–
organic framework (MOF) catalyst. The confined reaction space within the MOF pores …

Total syntheses of certain asperversiamides, linearly-fused and prenylated indole alkaloids

Z Xu, XT Liang, P Lan, MG Banwell - Organic Chemistry Frontiers, 2024 - pubs.rsc.org
Biogenetically patterned total syntheses of the prenylated indole alkaloids asperversiamides
B, D, E, G and J as well as dihydrocarneamide A have been realised while a related …

[PDF][PDF] BIOLOGICAL POTENTIAL OF INDOLE DERIVATIVES IN RECENT RESEARCH

AK Yadav, MK Shukla, R Bano - researchgate.net
Numerous indole-containing bioactive aromatic molecules shown biological and medical
uses. Numerous significant synthetic medicine compounds contain the indole scaffold …