Recent progress in synthetic applications of hypervalent iodine (III) reagents

A Yoshimura, VV Zhdankin - Chemical Reviews, 2024 - ACS Publications
Hypervalent iodine (III) compounds have found wide application in modern organic
chemistry as environmentally friendly reagents and catalysts. Hypervalent iodine reagents …

Synthesis and transformations of NH‐sulfoximines

M Andresini, A Tota, L Degennaro… - … –A European Journal, 2021 - Wiley Online Library
Recent years have seen a marked increase in the occurrence of sulfoximines in the
chemical sciences, often presented as valuable motifs for medicinal chemistry. This has …

Super Long‐Cycling All‐Solid‐State Battery with Thin Li6PS5Cl‐Based Electrolyte

S Liu, L Zhou, J Han, K Wen, S Guan… - Advanced Energy …, 2022 - Wiley Online Library
All‐solid‐state batteries (ASSBs) using sulfide electrolytes have attracted ever‐increasing
interest due to high ionic conductivity of the sulfides. Nevertheless, a thin, strong solid‐state …

Modern stereoselective synthesis of chiral sulfinyl compounds

E Wojaczyńska, J Wojaczyński - Chemical reviews, 2020 - ACS Publications
Chiral sulfinyl compounds, sulfoxides, sulfoximines, sulfinamides, and other derivatives, play
an important role in asymmetric synthesis as versatile auxiliaries, ligands, and catalysts …

Asymmetric synthesis of S (IV) and S (VI) stereogenic centers

X Zhang, F Wang, CH Tan - JACS Au, 2023 - ACS Publications
Sulfur can form diverse S (IV) and S (VI) stereogenic centers, of which some have gained
significant attention recently due to their increasing use as pharmacophores in drug …

How do we address neglected sulfur pharmacophores in drug discovery?

MJ Tilby, MC Willis - Expert Opinion on Drug Discovery, 2021 - Taylor & Francis
Sulfur is an ubiquitous heteroatom in medicinal chemistry [1]. Its prevalence is often credited
to its ability to exist in many oxidation states, whilst also being capable of bonding to a …

Harnessing sulfinyl nitrenes: a unified one-pot synthesis of sulfoximines and sulfonimidamides

TQ Davies, MJ Tilby, J Ren, NA Parker… - Journal of the …, 2020 - ACS Publications
Sulfoximines and sulfonimidamides are promising compounds for medicinal and
agrochemistry. As monoaza analogues of sulfones and sulfonamides, respectively, they …

Stereospecific reaction of sulfonimidoyl fluorides with Grignard reagents for the synthesis of enantioenriched sulfoximines

S Greed, O Symes, JA Bull - Chemical Communications, 2022 - pubs.rsc.org
Sulfonimidoyl halides have previously shown poor stability and selectivity in reaction with
organometallic reagents. Here we report the preparation of enantioenriched sulfonimidoyl …

Synthesis of sulfoximines by copper-catalyzed oxidative coupling of sulfinamides and aryl boronic acids

X Zou, H Wang, B Gao - Organic Letters, 2023 - ACS Publications
A novel copper-catalyzed cross-coupling reaction of sulfinamides and aryl boronic acids is
developed. The reaction is highly chemoselective and stereospecific, which allows mild …

Photoredox alkylation of sulfinylamine enables the synthesis of highly functionalized sulfinamides and S (VI) derivatives

L Li, S Zhang, Y Chen, X Cui, G Zhao, Z Tang… - ACS Catalysis, 2022 - ACS Publications
Sulfinamides have widespread applications in organic synthesis, especially for the
preparation of S (VI) derivatives such as sulfonimidamide and sulfonimidate ester. The …